Preparation and characterization of Ba2TiSi2O8 ferroelectric films produced by sol-gel method

被引:17
作者
Dai, WK
Zhu, MK
Hou, YD
Wang, H
Yan, H
Shao, MM
Chen, XY
Xu, JB
机构
[1] Beijing Univ Technol, Inst Mat Sci & Engn, Key Lab Adv Funct Mat, Beijing 100022, Peoples R China
[2] Beijing Changfeng Surface Acoust Wave Device Corp, Beijing 100891, Peoples R China
[3] CUHK, Dept Elect Engn, Shatin, Hong Kong, Peoples R China
基金
中国国家自然科学基金;
关键词
fresnoite; Ba2TiSi2O8; thin film; sol-gel; crystallization;
D O I
10.1016/j.matlet.2004.05.021
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Fresnoite (Ba2TiSi2O8, BTS) thin films were grown on polished Si(100) substrates by sol-gel method. The films were characterized using Fourier transform infrared spectroscopy (FTIR), Raman scattering spectroscopy, X-ray diffraction (XRD) and atom force microscopy (AFM). The results reveal that the crystallinity of fresnoite thin films increases and their structures become more compact as post-annealing temperature increases. Combined with XRD data, the strong FTIR peaks and Raman bands assigned to Ti-O and Si-O vibration indicate the formation of fresnoite phase in the films at a temperature of 750 degreesC. Besides, the AFM observation showed the films have a smooth surface, fine grains and dense structure. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:2927 / 2931
页数:5
相关论文
共 14 条
[1]  
BLASSE G, 1979, J INORG NUCL CHEM, V5, P639
[2]   Preparation of polar oriented Sr2TiSi2O8 films by surface crystallization of glass and second harmonic generation [J].
Ding, Y ;
Masuda, N ;
Miura, Y ;
Osaka, A .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1996, 203 :88-95
[3]   Fresnoite: A new ferroelectric mineral [J].
Foster, MC ;
Arbogast, DJ ;
Nielson, RM ;
Photinos, P ;
Abrahams, SC .
JOURNAL OF APPLIED PHYSICS, 1999, 85 (04) :2299-2303
[4]  
HAUSSUHL S, 1968, Z KRISTALLOGR, V103, P438
[5]  
KAPALAKRISHNAN J, 1999, J SOLID STATE CHEM, V148, P75
[6]  
KAWA PM, 1988, THESIS U WINDSOR ONT
[7]   NEW PIEZOELECTRIC CRYSTAL - SYNTHETIC FRESNOITE (BA2SI2TIO8) [J].
KIMURA, M ;
FUJINO, Y ;
KAWAMURA, T .
APPLIED PHYSICS LETTERS, 1976, 29 (04) :227-228
[8]   THE GROWTH-KINETICS OF RF-SPUTTERED BA2SI2TIO8 THIN-FILMS [J].
LI, Y ;
CHAO, BS ;
YAMAUCHI, H .
JOURNAL OF APPLIED PHYSICS, 1992, 71 (10) :4903-4907
[9]   RAMAN-STUDY OF FRESNOITE-TYPE MATERIALS - POLARIZED SINGLE-CRYSTAL, CRYSTALLINE POWDERS, AND GLASSES [J].
MARKGRAF, SA ;
SHARMA, SK ;
BHALLA, AS .
JOURNAL OF MATERIALS RESEARCH, 1993, 8 (03) :635-648
[10]   Single-crystal IR spectroscopic investigation on fresnoite, Sr-fresnoite and Ge-fresnoite [J].
Mayerhöfer, TG ;
Dunken, HH .
VIBRATIONAL SPECTROSCOPY, 2001, 25 (02) :185-195