Mixed-valence state of a one-dimensional platinum complex with a counter ion having two alkyl chains and its liquid crystal phase

We have investigated optical property and crystal structure of a one-dimensional halogen-bridged platinum complex (MX chain compound) with a counter ion having two alkyl chains, [Pt(en)(2)][PtCl2(en)(2)]{(CH3(CH2)(7)CO2)(2)CH2CHSO3}(4).2H(2)O, to elucidate influence of molecular fastener effect of the long alkyl chain on mixed-valence state of the platinum atoms. Thermal-behavior observations of the complex were also performed using a polarizing optical microscope without and with crossed nicols to examine thermal change of the mixed-valence state and appearance of the liquid crystal phase. Consequently, the complex has exhibited that the interaction between the platinum atoms is strengthened and the Pt-II-Pt-IV distance is shortened by doubling the number of alkyl chains around the platinum complex moieties compared with a corresponding PtCl chain complex with a single alkyl chain counter ion. We have also observed a texture of liquid crystal at about 200 degreesC.