A 3D interlocked structure from a 2D template: Structural requirements for the assembly of a square-planar metal-coordinated [2]rotaxane

被引：118

作者：

Fuller, AM ^{[1
]}

Leigh, DA ^{[1
]}

Lusby, PJ ^{[1
]}

Oswald, IDH ^{[1
]}

Parsons, S ^{[1
]}

Walker, DB ^{[1
]}

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 30期

关键词：

coordination modes; palladium; rotaxanes; template synthesis;

D O I：

10.1002/anie.200353622

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One step beyond: The synthesis of a three-dimensional interlocked molecular architecture (a rotaxane) from a two-dimensional square-planar metal template (see scheme) has been achieved. A combination of steric and electronic factors direct the synthesis in the third dimension, either by promoting or preventing interlocking.

引用

页码：3914 / 3918

页数：5

共 42 条

[11] Quantitative comparison of kinetic stabilities of metallomacrocycle-based rotaxanes [J].

Chang, SY ;

Jang, HY ;

Jeong, KS .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (07) :1535-1541

[12] Synthesis and characterization of a metallocycle-based molecular shuttle [J].

Chang, SY ;

Jeong, KS .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (10) :4014-4019

[13]

Chang SY, 2001, CHEM-EUR J, V7, P2687, DOI 10.1002/1521-3765(20010618)7:12<2687::AID-CHEM26870>3.0.CO

[14]

2-A

[15] Shuttles and muscles:: Linear molecular machines based on transition metals [J].

Collin, JP ;

Dietrich-Buchecker, C ;

Gaviña, P ;

Jimenez-Molero, MC ;

Sauvage, JP .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (06) :477-487

[16] Zwitterionic [2]rotaxanes utilising anionic transition metal stoppers [J].

Davidson, GJE ;

Loeb, SJ ;

Parekh, NA ;

Wisner, JA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (21) :3135-3136

[17] A NEW FAMILY OF MOLECULES - METALLO-CATENANES [J].

DIETRICHBUCHECKER, CO ;

SAUVAGE, JP ;

KINTZINGER, JP .

TETRAHEDRON LETTERS, 1983, 24 (46) :5095-5098

[18] Palladium(II)-directed formation of pseudo-rotaxanes: the 3+1 approach to threaded species using square-planar geometries [J].

Hamann, C ;

Kern, JM ;

Sauvage, JP .

DALTON TRANSACTIONS, 2003, (19) :3770-3775

[19] An organometallic B-12-rotaxane and a B-12-dimer, relaxed and loaded forms of a molecular spring [J].

Hannak, RB ;

Farber, G ;

Konrat, R ;

Krautler, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (09) :2313-2314

[20] Magic rod rotaxanes: The hydrogen bond-directed synthesis of molecular shuttles under thermodynamic control [J].

Hannam, JS ;

Kidd, TJ ;

Leigh, DA ;

Wilson, AJ .

ORGANIC LETTERS, 2003, 5 (11) :1907-1910

← 1 2 3 4 5 →