A 3D interlocked structure from a 2D template: Structural requirements for the assembly of a square-planar metal-coordinated [2]rotaxane

被引：118
作者：
Fuller, AM [1 ]
Leigh, DA [1 ]
Lusby, PJ [1 ]
Oswald, IDH [1 ]
Parsons, S [1 ]
Walker, DB [1 ]
机构：
[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 30期
关键词：
coordination modes; palladium; rotaxanes; template synthesis;
D O I：
10.1002/anie.200353622
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
One step beyond: The synthesis of a three-dimensional interlocked molecular architecture (a rotaxane) from a two-dimensional square-planar metal template (see scheme) has been achieved. A combination of steric and electronic factors direct the synthesis in the third dimension, either by promoting or preventing interlocking.
引用
收藏
页码：3914 / 3918
页数：5
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