A 3D interlocked structure from a 2D template: Structural requirements for the assembly of a square-planar metal-coordinated [2]rotaxane

被引：118

作者：

Fuller, AM ^{[1
]}

Leigh, DA ^{[1
]}

Lusby, PJ ^{[1
]}

Oswald, IDH ^{[1
]}

Parsons, S ^{[1
]}

Walker, DB ^{[1
]}

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 30期

关键词：

coordination modes; palladium; rotaxanes; template synthesis;

D O I：

10.1002/anie.200353622

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One step beyond: The synthesis of a three-dimensional interlocked molecular architecture (a rotaxane) from a two-dimensional square-planar metal template (see scheme) has been achieved. A combination of steric and electronic factors direct the synthesis in the third dimension, either by promoting or preventing interlocking.

引用

页码：3914 / 3918

页数：5

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