Coordination polymers for catalysis: enhancement of catalytic activity through hierarchical structuring

被引:51
作者
Bu, Fan-Xing [1 ]
Hu, Ming [1 ]
Xu, Li [1 ]
Meng, Qi [1 ]
Mao, Gui-Yun [1 ]
Jiang, Dong-Mei [1 ]
Jiang, Ji-Sen [1 ]
机构
[1] E China Normal Univ, Ctr Funct Nanomat & Devices, Dept Phys, Shanghai 200241, Peoples R China
基金
中国国家自然科学基金;
关键词
METAL-ORGANIC FRAMEWORKS; ONE-POT SYNTHESIS; CONTROLLABLE SYNTHESIS; STORAGE APPLICATIONS; MESOCRYSTALS; NANOPARTICLES; GROWTH; MORPHOLOGY; OXIDATION; HYDROGEN;
D O I
10.1039/c4cc02909g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We utilized a novel strategy, hierarchical structuring, to enhance the catalytic activity of coordination polymers. Hierarchical Prussian white crystals with hollow structures and kinked surfaces were synthesized by using a self-aggregation and etching strategy. The hierarchical structure significantly enhanced the catalytic activity of Prussian white in the degradation of methylene blue in comparison to the non-hierarchical Prussian white crystals.
引用
收藏
页码:8543 / 8546
页数:4
相关论文
共 62 条
[1]   Prussian White as a highly active molecular catalyst for proton reduction [J].
Abe, T ;
Taguchi, F ;
Tokita, S ;
Kaneko, M .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 126 (2-3) :L89-L92
[2]   Mesoporous Metallic Cells: Design of Uniformly Sized Hollow Mesoporous PtRu Particles with Tunable Shell Thicknesses [J].
Ataee-Esfahani, Hamed ;
Liu, Jian ;
Hu, Ming ;
Miyamoto, Nobuyoshi ;
Tominaka, Satoshi ;
Wu, Kevin C. W. ;
Yamauchi, Yusuke .
SMALL, 2013, 9 (07) :1047-1051
[3]   One-pot synthesis of Prussian blue superparticles from reverse microemulsion [J].
Bu, Fan-Xing ;
Du, Chen-Jie ;
Zhang, Qing-Hong ;
Jiang, Ji-Sen .
CRYSTENGCOMM, 2014, 16 (15) :3113-3120
[4]   Hopper-like framework growth evolution in a cubic system: a case study of Cu2O [J].
Chen, Kunfeng ;
Song, Shuyan ;
Xue, Dongfeng .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2013, 46 :1603-1609
[5]   Mesocrystals:: Inorganic superstructures made by highly parallel crystallization and controlled alignment [J].
Cölfen, H ;
Antonietti, M .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (35) :5576-5591
[6]   Switching between kinetic and thermodynamic control: calcium carbonate growth in the presence of a simple alcohol [J].
Dickinson, SR ;
McGrath, KM .
JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (04) :928-933
[7]   Using Functional Nano- and Microparticles for the Preparation of Metal-Organic Framework Composites with Novel Properties [J].
Doherty, Cara M. ;
Buso, Dario ;
Hill, Anita J. ;
Furukawa, Shuhei ;
Kitagawa, Susumu ;
Falcaro, Paolo .
ACCOUNTS OF CHEMICAL RESEARCH, 2014, 47 (02) :396-405
[8]   Mesocrystals: Syntheses in metals and applications [J].
Fang, Jixiang ;
Ding, Bingjun ;
Gleiter, Herbert .
CHEMICAL SOCIETY REVIEWS, 2011, 40 (11) :5347-5360
[9]   PREPARATION, CLATHRATION ABILITY, AND CATALYSIS OF A 2-DIMENSIONAL SQUARE NETWORK MATERIAL COMPOSED OF CADMIUM(II) AND 4,4'-BIPYRIDINE [J].
FUJITA, M ;
KWON, YJ ;
WASHIZU, S ;
OGURA, K .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (03) :1151-1152
[10]   Ultrahigh Porosity in Metal-Organic Frameworks [J].
Furukawa, Hiroyasu ;
Ko, Nakeun ;
Go, Yong Bok ;
Aratani, Naoki ;
Choi, Sang Beom ;
Choi, Eunwoo ;
Yazaydin, A. Oezguer ;
Snurr, Randall Q. ;
O'Keeffe, Michael ;
Kim, Jaheon ;
Yaghi, Omar M. .
SCIENCE, 2010, 329 (5990) :424-428