Coordination copolymerization of three carboxylate linkers into a pillared layer framework

被引：45
作者：
Dutta, Ananya [1 ]
Wong-Foy, Antek G. [1 ]
Matzger, Adam J. [1 ,2 ]
机构：
[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
[2] Univ Michigan, Dept Macromol Sci & Engn, Ann Arbor, MI 48109 USA
来源：
CHEMICAL SCIENCE | 2014年 / 5卷 / 10期
关键词：
METAL-ORGANIC FRAMEWORK; SURFACE-AREAS; GAS-UPTAKE; PORE-SIZE; POLYMERS; MOLECULES; LIGAND; ADSORPTION; POROSITY; SORPTION;
D O I：
10.1039/c3sc53549e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Incorporation of three distinct linkers with identical functionality in a coordination copolymer is accomplished in materials designated UMCM-10, -11, and -12. Uniaxial lattice expansion, achieved in these highly porous and non-interpenetrated materials, is utilized in size-selective guest incorporation.
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收藏
页码：3729 / 3734
页数：6
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