h-MoO3 microrods grown on wood substrates through a low-temperature hydrothermal route and their optical properties

被引:17
|
作者
Hui, Bin [1 ,2 ]
Li, Guoliang [1 ,2 ]
Zhao, Xiping [3 ]
Wang, Lijuan [1 ,2 ]
Wu, Dianxiu [1 ,2 ]
Li, Jian [1 ,2 ]
Via, Brian K. [4 ]
机构
[1] Northeast Forestry Univ, Key Lab Biobased Mat Sci & Technol, Minist Educ, Harbin 150040, Peoples R China
[2] Northeast Forestry Univ, Mat Sci & Engn Coll, Harbin 150040, Peoples R China
[3] Henan Univ Sci & Technol, Coll Forestry, Luoyang 471003, Peoples R China
[4] Auburn Univ, Sch Forestry & Wildlife Sci, Forest Prod Dev Ctr, Auburn, AL 36849 USA
基金
中国国家自然科学基金;
关键词
OXIDE THIN-FILMS; MOLYBDENUM OXIDE; PHOTOCHROMIC PROPERTIES; METASTABLE H-MOO3; HEXAGONAL MOO3; FABRICATION; PRECIPITATION; PERFORMANCE; PYROLYSIS; COMPOSITE;
D O I
10.1007/s10854-016-5918-y
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Molybdenum trioxide (MoO3) films with optical properties were successfully grown on wood substrates using a low-temperature hydrothermal method. Scanning electron microscopy analysis shows that MoO3 thin films were composed of rods-like microstructures and the rod sizes increased as the initial pH value of the solution increased. X-ray diffraction studies indicate crystallinity was greatly improved by increasing the pH value of the precursor solution. Raman spectrum, X-ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy analysis further proves that pure MoO3 films could be grown on a wood substrate. The UV-Vis analysis suggests that the films exhibited better in response to UV light. The band gap energy estimated from the Kubelka-Munk function was found to be in the range of 2.847-2.974 eV. The results from thermogravimetric analysis and differential scanning calorimetry experiments imply that the films possessed good thermal stability.
引用
收藏
页码:3264 / 3271
页数:8
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