An Efficient Photocatalyst for the Azide-Alkyne Click Reaction Based on Direct Photolysis of a Copper(II)/Carboxylate Complex

被引：12

作者：

Guan, Xin ^{[1
]}

Zhang, Jing ^{[1
]}

Wang, Yuechuan ^{[1
]}

机构：

[1] Sichuan Univ, Coll Polymer Sci & Engn, State Key Lab Polymer Mat & Engn, Chengdu 610065, Peoples R China

来源：

CHEMISTRY LETTERS | 2014年 / 43卷 / 07期

关键词：

CHEMISTRY; CYCLOADDITION; PHOTOINITIATOR;

D O I：

10.1246/cl.140240

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photochemical processes provide a temporal and spatial control of the reaction, which offers an efficient way for chemical synthesis and affords extensive applications in materials science. In this study, a new photocatalyst system based on a Cu(II)/carboxylate complex was developed for photoinduced CuAAC reaction. The results show that the conversion was over 90% after irradiation for 30 min.

引用

页码：1073 / 1074

页数：2

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