Effects of Eu2+ Co-Doping on VUV Photoluminescence Properties of BaMgAl10O17:Mn2+ Phosphors for Plasma Display Panels

被引:35
作者
Moon, Taeho [1 ]
Hong, Gun Young [1 ]
Lee, Hong-Cheol [1 ]
Moon, Eun-A [1 ]
Jeoung, Byung Woo [1 ]
Hwang, Sun-Tae [1 ]
Kim, Je Seok [1 ]
Ryu, Byung-Gil [1 ]
机构
[1] LG Elect, Display Res & Dev Lab, Seoul 137724, South Korea
关键词
barium compounds; doping profiles; europium; magnesium compounds; manganese; materials preparation; phosphors; photoluminescence; plasma displays; LUMINESCENT PROPERTIES; ENERGY-TRANSFER; MN2+; SPECTROSCOPY;
D O I
10.1149/1.3126528
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The effects of Eu2+ co-doping were examined on vacuum ultraviolet (VUV) photoluminescence properties of BaMgAl10O17:Mn2+ phosphors. The BaMgAl10O17:Mn2+,Eu2+ phosphors were synthesized with various Eu concentrations ranging from 0 to 2 atom %. When Eu ions were added, the blue luminescence appeared with the decrease in the green luminescence. With increasing Eu concentration, the decay time (tau(1/10)) gradually decreased from 11.7 ms (0 atom %) to 3.5 ms (2 atom %). The energy-transfer efficiencies (eta(Mn -> Eu)) were analyzed with the average-decay time (tau(av)) acquired by a double-exponential fitting, and the 2 atom % Eu sample showed the energy-transfer efficiency of 19%.
引用
收藏
页码:J61 / J63
页数:3
相关论文
共 23 条
[1]   MN-2+ CONCENTRATION-EFFECT ON THE OPTICAL-PROPERTIES OF ZN2SIO4MN PHOSPHORS [J].
BARTHOU, C ;
BENOIT, J ;
BENALLOUL, P ;
MORELL, A .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (02) :524-528
[2]  
Blasse G., 1994, LUMINESCENT MAT, P1, DOI [10.1007/978-3-642-79017-1_1, DOI 10.1007/978-3-642-79017-1_1, 10.1007/978-3-642-79017-11, DOI 10.1007/978-3-642-79017-11]
[3]   Mechanisms of VUV damage in BaMgAl10O17:Eu2+ [J].
Dawson, B ;
Ferguson, M ;
Marking, G ;
Diaz, AL .
CHEMISTRY OF MATERIALS, 2004, 16 (25) :5311-5317
[4]   Characteristics of phosphor degradation in ac-driven plasma display panels [J].
Ha, Chang Hoon ;
Han, Bo Yong ;
Yoo, Jae Soo ;
Bae, Hyun Soo ;
Whang, Ki-Woong .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (09) :J230-J234
[5]   Improvement of discharge characteristics of the Zn2SiO4:Mn2+ phosphor layer in plasma display panels [J].
Hong, GY ;
Jeoung, BW ;
Jeon, BS ;
Yoo, JS ;
Ha, CH ;
Whang, KW .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (10) :H205-H209
[6]   Characterization of host-lattice emission and energy transfer in BaMgAl10O17:Eu2+ [J].
Howe, B ;
Diaz, AL .
JOURNAL OF LUMINESCENCE, 2004, 109 (01) :51-59
[7]   Luminescent properties of (Ba,Sr)MgAl10O17:Mn,Eu green phosphor prepared by spray pyrolysis under VUV excitation [J].
Jung, KY ;
Lee, HW ;
Kang, YC ;
Park, SB ;
Yang, YS .
CHEMISTRY OF MATERIALS, 2005, 17 (10) :2729-2734
[8]   Blue emitting BaMgAl10O17:Eu with a blue body color [J].
Jüstel, T ;
Bechtel, H ;
Mayr, W ;
Wiechert, DU .
JOURNAL OF LUMINESCENCE, 2003, 104 (1-2) :137-143
[9]   Thermoluminescence spectroscopy of Eu2+ and Mn2+ doped BaMgAl10O17 [J].
Jüstel, T ;
Lade, H ;
Mayr, W ;
Meijerink, A ;
Wiechert, DU .
JOURNAL OF LUMINESCENCE, 2003, 101 (03) :195-210
[10]  
Jüstel T, 2001, J LUMIN, V93, P179, DOI 10.1016/S0022-2313(01)00199-5