Galvanic Effect of Pyrite on Chalcopyrite Leaching in Sulfate-Chloride Media

被引：20
作者：
Ruiz, M. C. [1 ]
Montes, K. S. [1 ]
Padilla, R. [1 ]
机构：
[1] Univ Concepcion, Dept Met Engn, Concepcion, Chile
来源：
MINERAL PROCESSING AND EXTRACTIVE METALLURGY REVIEW | 2015年 / 36卷 / 01期
关键词：
sulfide chloride leaching; pyrite-chalcopyrite; galvanic effect; DISSOLUTION; NACL; MINERALS; KINETICS; CUFES2; OXYGEN; IONS; HCL;
D O I：
10.1080/08827508.2013.868349
中图分类号：
TF [冶金工业];
学科分类号：
0806 ;
摘要：
Chalcopyrite concentrate and mixtures of pyrite/chalcopyrite were leached in H2SO4-NaCl-O-2 solutions to assess the effect of pyrite on the chalcopyrite dissolution rate in this media. The results showed that the addition of pyrite increases the dissolution rate of chalcopyrite at short leaching times but the catalytic effect of pyrite decreases as the reaction progresses. Based on the experimental evidence, it was concluded that the presence of pyrite in the leaching of chalcopyrite in H2SO4-NaCl-O-2 solutions enhances the dissolution of copper through a galvanic interaction between pyrite and chalcopyrite. Additions of ferrous sulfate also increase chalcopyrite leaching rate effectively.
引用
收藏
页码：65 / 70
页数：6
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