Catalytic transformation of aldimine to ketimine by Wilkinson's complex through transimination

被引：43

作者：

Jun, CH ^{[1
]}

Hong, JB ^{[1
]}

机构：

[1] Yonsei Univ, Dept Chem, Seoul 120749, South Korea

来源：

ORGANIC LETTERS | 1999年 / 1卷 / 06期

关键词：

D O I：

10.1021/ol990158s

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The C-H bond activation in homogeneous catalysis is important for carbon skeleton construction through C-C bond formation. In this report, a new direct synthesis of ketimine from aldimine bearing no coordination site is demonstrated with high catalytic efficiency. Transimination is the major role for this catalytic reaction.

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页码：887 / 889

页数：3

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