Complete hydrogen release from aqueous ammonia-borane over a platinum-loaded titanium dioxide photocatalyst

被引:38
作者
Kamegawa, Takashi [1 ]
Nakaue, Takayuki [1 ,2 ]
机构
[1] Osaka Prefecture Univ, Nanosci & Nanotechnol Res Ctr, Naka Ku, Sakai, Osaka 5998570, Japan
[2] Osaka Prefecture Univ, Dept Appl Chem, Grad Sch Engn, Naka Ku, Sakai, Osaka 5998531, Japan
关键词
OXIDE PHOTOCATALYST; MESOPOROUS SILICA; GENERATION SYSTEM; STORAGE MATERIALS; ROOM-TEMPERATURE; TIO2; REGENERATION; HYDROLYSIS; PARTICLES; FUEL;
D O I
10.1039/c5cc06639e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Complete H-2 release from ammonia-borane (NH3BH3, AB) in water was achieved by using platinum-loaded TiO2 (Pt/TiO2) via two consecutive reaction steps, i.e., hydrolysis of AB and photocatalytic decomposition of thus formed NH3 in water, under inert conditions at 298 K.
引用
收藏
页码:16802 / 16805
页数:4
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