[Bmim]PF6-Promoted Ligandless Suzuki-Miyaura Coupling Reaction of Potassium Aryltrifluoroborates in Water

被引：37

作者：

Liu, Leifang ^{[1
]}

Dong, Yan ^{[1
]}

Pang, Bo ^{[1
]}

Ma, Jiahai ^{[1
]}

机构：

[1] Dezhou Univ, Key Lab Coordinat Chem & Funct Mat Univ Shandong, Dezhou 253023, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 79卷 / 15期

基金：

中国国家自然科学基金;

关键词：

PALLADIUM-CATALYZED SUZUKI; TEMPERATURE IONIC LIQUIDS; ARYL CHLORIDES; AQUEOUS-MEDIA; ARYLBORONIC ACIDS; PHOSPHINE-LIGANDS; ORGANIC-SYNTHESIS; EFFICIENT; HALIDES; NANOPARTICLES;

D O I：

10.1021/jo500840s

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Suzuki-Miyaura coupling reactions of potassium aryltrifluoroborates with aryl bromides in water are promoted by the addition of [bmim]PF6 using Pd(OAc)(2) as a catalyst and Na2CO3 as a base under air. The quantity of [bmim]PF6 used is crucial to the efficiency of the catalytic system. A wide range of biaryls and polyaryls can be easily prepared in good to excellent yields.

引用

页码：7193 / 7198

页数：6

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