Silver-Catalyzed Oxidative C(sp3)-P Bond Formation through C-C and P-H Bond Cleavage

被引：71

作者：

Li, Lili ^{[1
]}

Huang, Wenbin ^{[1
]}

Chen, Lijin ^{[1
]}

Dong, Jiaxing ^{[1
]}

Ma, Xuebing ^{[1
]}

Peng, Yungui ^{[1
]}

机构：

[1] Southwest Univ, Sch Chem & Chem Engn, 2 Tiansheng Rd, Chongqing 400715, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2017年 / 56卷 / 35期

关键词：

C C bond cleavage; cross-coupling; C(sp(3))P bond formation; 1,3-dicarbonyl compounds; silver; BETA-KETOPHOSPHINE OXIDES; DIALKYL PHOSPHITES; AEROBIC OXYPHOSPHORYLATION; CARBONYL-COMPOUNDS; PHOSPHONATES; FUNCTIONALIZATION; PHOSPHORYLATION; METAL; KETOESTERS; KETONES;

D O I：

10.1002/anie.201704910

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The silver-catalyzed oxidative C(sp(3))-H/P-H cross-coupling of 1,3-dicarbonyl compounds with H-phosphonates, followed by a chemo- and regioselective C(sp(3))-C(CO) bond-cleavage step, provided heavily functionalized beta-ketophosphonates. This novel method based on a readily available reaction system exhibits wide scope, high functional-group tolerance, and exclusive selectivity.

引用

页码：10539 / 10544

页数：6

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