Molecular design of mononuclear complexes of acyclic Schiff-base ligands

被引：110

作者：

Garnovskii, A. D. ^{[1
]}

Vasilchenko, I. S. ^{[2
]}

Garnovskii, D. A. ^{[1
]}

Kharisov, B. I. ^{[3
]}

机构：

[1] So Fed Univ, Inst Phys & Organ Chem, Rostov Na Donu 344090, Russia

[2] Russian Acad Sci, So Sci Ctr, Rostov Na Donu 344006, Russia

[3] Univ Autonoma Nuevo Leon, Fac Ciencias Quim, CIIDIT, San Nicolas De Los Garza 66450, NL, Mexico

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 62卷 / 02期

关键词：

Schiff bases; Mononuclear complexes; Di- and oligodentate azomethine ligands with N; C-; N; N-; P-; O-; S-; Se-; Te-donor centers; Te- Salen chelates; Standard and nonstandard structures; RAY CRYSTAL-STRUCTURES; NEUTRAL NICKEL-CATALYSTS; N-SUBSTITUTED THIOSALICYLIDENEIMINES; IMIDAZOLIDINE RING HYDROLYSIS; ELECTRON-TRANSFER KINETICS; PI-STACKING INTERACTIONS; DNA CLEAVAGE ACTIVITY; SALEN-TYPE COMPLEXES; X-RAY; COPPER(II) COMPLEXES;

D O I：

10.1080/00958970802398178

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Data on molecular design of various types of mononuclear complexes of Schiff bases are generalized. Factors for variation of fine structure of Schiff-base ligand systems (metallocycle sizes and their number, nature of donor centers, aldehyde and amine fragments, co-ligands) are examined. A systematization of Salen complexes is offered. Electronic configurations of p- and d-metals in the coordination and organometallic compounds are taken into account in a series of chelate structures. Non-standard structures are emphasized, including various ligand chelates and molecular complexes.

引用

页码：151 / 204

页数：54

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