Molecular design of mononuclear complexes of acyclic Schiff-base ligands

被引：110
作者：
Garnovskii, A. D. [1 ]
Vasilchenko, I. S. [2 ]
Garnovskii, D. A. [1 ]
Kharisov, B. I. [3 ]
机构：
[1] So Fed Univ, Inst Phys & Organ Chem, Rostov Na Donu 344090, Russia
[2] Russian Acad Sci, So Sci Ctr, Rostov Na Donu 344006, Russia
[3] Univ Autonoma Nuevo Leon, Fac Ciencias Quim, CIIDIT, San Nicolas De Los Garza 66450, NL, Mexico
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 62卷 / 02期
关键词：
Schiff bases; Mononuclear complexes; Di- and oligodentate azomethine ligands with N; C-; N; N-; P-; O-; S-; Se-; Te-donor centers; Te- Salen chelates; Standard and nonstandard structures; RAY CRYSTAL-STRUCTURES; NEUTRAL NICKEL-CATALYSTS; N-SUBSTITUTED THIOSALICYLIDENEIMINES; IMIDAZOLIDINE RING HYDROLYSIS; ELECTRON-TRANSFER KINETICS; PI-STACKING INTERACTIONS; DNA CLEAVAGE ACTIVITY; SALEN-TYPE COMPLEXES; X-RAY; COPPER(II) COMPLEXES;
D O I：
10.1080/00958970802398178
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Data on molecular design of various types of mononuclear complexes of Schiff bases are generalized. Factors for variation of fine structure of Schiff-base ligand systems (metallocycle sizes and their number, nature of donor centers, aldehyde and amine fragments, co-ligands) are examined. A systematization of Salen complexes is offered. Electronic configurations of p- and d-metals in the coordination and organometallic compounds are taken into account in a series of chelate structures. Non-standard structures are emphasized, including various ligand chelates and molecular complexes.
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页码：151 / 204
页数：54
相关论文
共 488 条
[1]  
ABAKAROV GM, 2007, COMMUNICATION
[2]   Synthesis and characterization of a cationic oxorhenium(V) complex containing the pentadentate N3O2-donor ligand bis(N-methylsalicylideneiminopropyl) amine [J].
Abrahams, Abubak'r ;
Gerber, Thomas I. A. ;
Luzipo, Dibanisile R. ;
Mayer, Peter .
JOURNAL OF COORDINATION CHEMISTRY, 2007, 60 (20) :2215-2220
[3]   Synthesis and spectroscopic studies on ternary bis-Schiff-base complexes having oxygen and/or nitrogen donors [J].
Abu-Hussen, AAA .
JOURNAL OF COORDINATION CHEMISTRY, 2006, 59 (02) :157-176
[4]   Synthesis, characterisation and X-ray structure of an azido adduct of a tridentate (NNO) Schiff base nickel(II) complex [J].
Adhikary, Chandan ;
Mal, Dasarath ;
Chaudhuri, Siddhartha ;
Koner, Subratanath .
JOURNAL OF COORDINATION CHEMISTRY, 2006, 59 (07) :699-704
[5]   Syntheses, crystal structures and electronic properties of a series of copper(II) complexes with 3,5-halogen-substituted Schiff base ligands and their solutions [J].
Akitsu, T ;
Einaga, Y .
POLYHEDRON, 2005, 24 (18) :2933-2943
[6]   Synthesis, crystal structures and electronic properties of Schiff base nickel (II) complexes: Towards solvatochromism induced by a photochromic solute [J].
Akitsu, T ;
Einaga, Y .
POLYHEDRON, 2005, 24 (14) :1869-1877
[7]   Diaqua[N,N′-bis(5-methoxysalicylidene)ethylenediaminato-κ4O,N,N′,O′]manganese (III) perchlorate, aqua [N,N′-bis(3,5-dichlorosalicylidene)ethylenediaminato-κ4O,N,N′,O′](methanol-κO)manganese(III) perchlorate and bis[μ-N,N′-bis(3-methoxysalicylidene)ethylenediaminato-κ5O,N,N′,O′:O]bis[(methanol-κO)manganese(III)] diperchlorate [J].
Akitsu, T ;
Takeuchi, Y ;
Einaga, Y .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2005, 61 (07) :M324-M328
[8]   Diaqua[(1R,2R)-N,N′-bis(3,5-dibromosalicylidene)cyclohexane-1,2-diamine-κ4O,N,N′,O′]manganese(III) perchlorate dihydrate [J].
Akitsu, T ;
Takeuchi, Y ;
Einaga, Y .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 :M772-M774
[9]   Bis[(R)-3,5-dichloro-N-(1-phenylethyl)salicylideneaminato-κ2N,O]- copper(II) and bis[(R)-3-ethoxy-N-(1-phenylethyl)salicylideneaminato-κ2N,O]copper(II) [J].
Akitsu, T ;
Einaga, Y .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2004, 60 :M640-M642
[10]   Bis[(S)-N-2-(2-butyl)-3,5-dichlorosalicylidene-aminato-κ2N,O]copper(II) [J].
Akitsu, T ;
Einaga, Y .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 :M1605-M1607
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