Convenient and efficient synthesis of functionalized unsymmetrical Z-alkenyl disulfanes

被引：10

作者：

Musiejuk, M. ^{[1
]}

Doroszuk, J. ^{[1
]}

Witt, D. ^{[1
]}

机构：

[1] Gdansk Univ Technol, Fac Chem, Dept Organ Chem, Narutowicza 11-12, PL-80233 Gdansk, Poland

来源：

RSC ADVANCES | 2018年 / 8卷 / 18期

关键词：

DISULFIDE EXCHANGE-REACTION; RING-OPENING REACTIONS; S BOND FORMATION; SYMMETRICAL TRISULFIDES; Z-AJOENE; CHEMISTRY; THIOLS; AGENTS; SULFENYLATION; ESTERS;

D O I：

10.1039/c8ra00659h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We developed a simple and efficient method for the synthesis of functionalized unsymmetrical Z-alkenyl disulfanes under mild conditions in moderate to good yields. The designed method is based on the reaction of Z-alkenyl thiotosylates with thiols in the presence of base. The developed method allows the preparation of unsymmetrical Z-alkenyl disulfanes bearing additional hydroxy, carboxy, or amino functionalities.

引用

页码：9718 / 9722

页数：5

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