A Facile and Green Route for Conversion of Bifunctional Epoxide and Vegetable Oils to Cyclic Carbonate: A Green Route to CO2 Fixation

被引：26
作者：
Farhadian, Abdolreza [1 ]
Afshani, Meisam Babapour Gol [1 ]
Miyardan, Ahmad Babaei [1 ]
Nabid, Mohammad Reza [1 ]
Safari, Nasser [1 ]
机构：
[1] Shahid Beheshti Univ, Dept Chem & Petr, Fac Sci, Tehran 198396313, Iran
来源：
CHEMISTRYSELECT | 2017年 / 2卷 / 04期
关键词：
atmospheric pressure; bifunctional epoxides; carbonatated oils; CO2; fixation; porphyrin; DIOXIDE FIXATION; OLEFIN EPOXIDATION; IONIC LIQUID; PORPHYRIN; CATALYST; COPOLYMERIZATION; CAPTURE; CYCLOADDITION; POLYURETHANES; METALLOPORPHYRINS;
D O I：
10.1002/slct.201601891
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A porphyrin based catalytic system with three metals of Manganese, Zinc and Iron and quaternary ammonium salt as co-catalyst showed very high selectivity for CO2 fixation reaction of different epoxide monomers for synthesizing cyclic carbonates. The reaction showed quantitative yields under solvent-free and atmospheric pressure. Quaternary ammonium salts were able to catalyse these reactions singlehandedly, thus their mole ratios were decreased to investigate metalloporphyrins effect. After three cycles of reusing, this catalytic system showed minor reduction in activity and no weight loss. Also, manganese porphyrin has high ability to convert bifunctional epoxides (yield 98% in 4h) and vegetable oil by CO2 (yield 99% in 30h) to cyclic carbonates at ambient condition.
引用
收藏
页码：1431 / 1435
页数：5
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