A simple amide protecting group: synthesis of oligoamides of Nylon 6

被引:26
作者
Brooke, GM [1 ]
Mohammed, S [1 ]
Whiting, MC [1 ]
机构
[1] UNIV BRISTOL, SCH CHEM, BRISTOL BS8 1TS, AVON, ENGLAND
关键词
D O I
10.1039/a703607h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The 4-methoxybenzyl group (R) in amide groups NR(C=O) renders all intermediates in the synthesis of oligomers of Nylon 6 soluble in common solvents and is readily removed in boiling trifluoroacetic acid.
引用
收藏
页码:1511 / 1512
页数:2
相关论文
共 10 条
[1]   On spherulitic growth in a monodisperse paraffin [J].
Bassett, DC ;
Olley, RH ;
Sutton, SJ ;
Vaughan, AS .
MACROMOLECULES, 1996, 29 (05) :1852-1853
[2]   Intermolecular forces and chain configuration in linear polymers - The effect of N-methylation on the X-ray structures and properties of linear polyamides [J].
Bayer, WO ;
Fuller, CS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1943, 65 :1120-1130
[3]  
BODANSZKY M, 1984, PRACTICE PEPTIDE SYN, P145
[4]  
BRIGGS BS, 1946, IND ENG CHEM, V38, P1016
[5]   Versatile process for the syntheses of very long chain alkanes, functionalised derivatives and some branched chain hydrocarbons [J].
Brooke, GM ;
Burnett, S ;
Mohammed, S ;
Proctor, D ;
Whiting, MC .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1996, (13) :1635-1645
[6]  
Carothers W. H, 1938, US Patent, Patent No. [2,130,523, 2130523]
[7]  
GREENE TW, 1991, PROTECTIVE GROUPS OR, P397
[8]  
LEWIS JR, 1951, CHEM IND-LONDON, P958
[9]   ELASTIC N-SUBSTITUTED POLYAMIDES [J].
WITTBECKER, EL ;
HOUTZ, RC ;
WATKINS, WW .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1948, 40 (05) :875-879
[10]  
Zahn H., 1963, ANGEW CHEM INT EDIT, V2, P410, DOI [10.1002/anie.196304101, DOI 10.1002/ANIE.196304101]