Kinetic studies on bismaleimide polymerization using inverse gas chromatography

被引：0

作者：

Tripathi, VS

Lal, D

Aggarwal, SK

Sen, AK

机构：

[1] Def. Mat. and Strs. R. and D. Estab., DMSRDE Post Office, Kanpur, G. T. Road

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1997年 / 66卷 / 08期

关键词：

polymerization kinetics; bismaleimide; inverse gas chromatography; dimethyl formamide; differential scanning calorimetry;

D O I：

10.1002/(SICI)1097-4628(19971121)66:8<1613::AID-APP23>3.0.CO;2-2

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Kinetics of polymerization of 4,4'-bismalemidodiphenyl methane (BMI) were studied in the temperature range of 158-222 degrees C by inverse gas chromatography (IGC) technique. BMI was synthesized and purified and then coated on DMCS treated chromosorb for preparation of GC column. Retention behavior of dimethyl formamide was studied at different temperatures and at different time intervals to follow the phase changes and kinetics of polymerization, respectively. The kinetic data obtained by IGC were compared with those obtained by differential scanning calorimetry. (C) 1997 John Wiley & Sons, Inc.

引用

页码：1613 / 1619

页数：7

共 12 条

[1] THE APPLICATION OF DIFFERENTIAL THERMAL ANALYSIS TO THE STUDY OF REACTION KINETICS
BORCHARDT, HJ
DANIELS, F
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (01) : 41 - 46
[2] FEILDMAN D, 1988, J POLYM SCI A, V26, P973
[3] FLORENCE M, 1987, J POLYM, V28, P2275
[4] ADDITION POLYIMIDES .1. KINETICS OF CURE REACTION AND THERMAL-DECOMPOSITION OF BISMALEIMIDES
NINAN, KN
KRISHNAN, K
MATHEW, J
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1986, 32 (07) : 6033 - 6042
[5] ON ESTIMATING ACTIVATION ENERGIES WITH A DIFFERENTIAL SCANNING CALORIMETER
ROGERS, RN
MORRIS, ED
[J]. ANALYTICAL CHEMISTRY, 1966, 38 (03) : 412 - &
[6] ESTIMATION OF PREEXPONENTIAL FACTOR FROM THERMAL DECOMPOSITION CURVE OF AN UNWEIGHED SAMPLE
ROGERS, RN
SMITH, LC
[J]. ANALYTICAL CHEMISTRY, 1967, 39 (08) : 1024 - &
[7] SEN AK, 1991, RES IND, V36, P69
[8] TURGANE AV, 1992, J APPL POLYM SCI, V46, P1125
[9] Varma IK, 1983, U. S. Patent, Patent No. 4395557
[10] VARMA IK, 1981, Patent No. 4276344

← 1 2 →