X-ray structure of [Os3(CO)10(μ-Ph2PCH2PPh2)]

被引：24

作者：

Azam, KA

Hursthouse, MB

Kabir, SE

Malik, KMA

Mottalib, MA

机构：

[1] Cardiff Univ, Dept Chem, Cardiff CF1 3TB, S Glam, Wales

[2] Jahangirnagar Univ, Dept Chem, Dhaka 1342, Bangladesh

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1999年 / 29卷 / 07期

基金：

英国工程与自然科学研究理事会;

关键词：

x-ray structure; osmium; diphenylphosphinomethane; carbonyl; cluster;

D O I：

10.1023/A:1009551905096

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Decacarbonyl-mu-bis (diphenylphosphino)methane triosmium crystallizes in the monoclinic space group P2(1)/c with a = 24.422(5), b = 12.381(2), c = 24.788(5) Angstrom, beta = 103.69(3)degrees V = 7282 (2) Angstrom(3), and Z = 8. The molecule consists of a triangular arrangement of osmium atoms with the organic ligand bridging two adjacent osmium atoms at equatorial sites. The Os-Os distances lie in the close range 2.8563(9)-2.8895(11) Angstrom with an average value of 2.87(1) Angstrom.

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页码：813 / 818

页数：6

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