Structure of the photocolored 2-(2′,4′-dinitrobenzyl)pyridine crystal:: Two-photon induced solid-state proton transfer with minor structural perturbation

被引：52

作者：

Naumov, P ^{[1
]}

Sekine, A ^{[1
]}

Uekusa, H ^{[1
]}

Ohashi, Y ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Chem & Mat Sci, Meguro Ku, Tokyo 1528551, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 29期

关键词：

D O I：

10.1021/ja0170908

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The X-ray structure of the blue phototautomer of 2-(2′,4′-dinitrobenzyl)pyridine (DNBP) produced by two-photon excitation in a single crystal is the first direct evidence of a product in the DNBP photochromic family. A nitro-assisted proton transfer mechanism is attributed to the photocoloration of solid DNBP. Copyright © 2002 American Chemical Society.

引用

页码：8540 / 8541

页数：2

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