The influence of Ti capping layers on CoSi2 formation

被引:33
作者
Detavernier, C
Van Meirhaeghe, RL
Cardon, F
Donaton, RA
Maex, K
机构
[1] Univ Ghent, Lab Kristallog Studie Vaste Stof, Vakgrp Vaste Stofwetenschappen, B-9000 Ghent, Belgium
[2] IMEC, B-3001 Louvain, Belgium
[3] Katholieke Univ Leuven, INSYS, B-3001 Louvain, Belgium
关键词
cobalt silicide; titanium capping layer; oxygen contamination; silicidation;
D O I
10.1016/S0167-9317(99)00272-5
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Cobalt silicide formation is very sensitive to the presence of oxygen. Oxygen contamination may originate from different sources: impurities in the annealing ambient, oxygen incorporated within the deposited Co layer and interfacial oxide at the Co/Si interface. In this work, it is shown that the cause of the sensitivity towards oxygen contamination is the formation of a SiOx diffusion barrier between CoSi and the unreacted Co. This causes an increase in the activation energy for CoSi formation. Furthermore, we will show that a titanium capping layer eliminates the sensitivity of CoSi2 formation for oxygen contamination, thus improving the formation of CoSi2 layers. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:125 / 132
页数:8
相关论文
共 12 条
[1]  
Besser P. R., 1998, MRS S P
[2]   GROWTH OF EPITAXIAL COSI2 ON (100)SI [J].
DASS, MLA ;
FRASER, DB ;
WEI, CS .
APPLIED PHYSICS LETTERS, 1991, 58 (12) :1308-1310
[3]   THE INFLUENCE OF IMPURITIES ON COBALT SILICIDE FORMATION [J].
FREITAS, WJ ;
SWART, JW .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (10) :3067-3070
[4]   Silicides and ohmic contacts [J].
Gambino, JP ;
Colgan, EG .
MATERIALS CHEMISTRY AND PHYSICS, 1998, 52 (02) :99-146
[5]   LOW-TEMPERATURE SURFACE CLEANING OF SILICON AND ITS APPLICATION TO SILICON MBE [J].
ISHIZAKA, A ;
SHIRAKI, Y .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1986, 133 (04) :666-671
[6]  
MAEX K, 1993, MAT SCI ENG R, V11, P53
[7]  
MAEX K, 1998, MRS S P
[8]   SILICIDE FORMATION FOR CO/TI/SI STRUCTURES PROCESSED BY RTP UNDER VACUUM [J].
SETTON, M ;
VANDERSPIEGEL, J .
APPLIED SURFACE SCIENCE, 1989, 38 (1-4) :62-71
[9]   Formation of CoTi barrier and increased thermal stability of CoSi2 film in Ti capped Co/Si(100) system [J].
Sohn, DK ;
Park, JS ;
Lee, BH ;
Bae, JU ;
Byun, JS ;
Kim, JJ .
APPLIED PHYSICS LETTERS, 1998, 73 (16) :2302-2304
[10]   INCREASED UNIFORMITY AND THERMAL-STABILITY OF COSI2 THIN-FILMS BY TI CAPPING [J].
TUNG, RT ;
SCHREY, F .
APPLIED PHYSICS LETTERS, 1995, 67 (15) :2164-2166