Perfluoropentaphenylborole: A New Approach to Lewis Acidic, Electron-Deficient Compounds

被引：36

作者：

Huynh, Keith ^{[1
]}

Vignolle, Joan ^{[1
]}

Tilley, T. Don ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 16期

关键词：

electron-deficient compounds; fluoroaryl boranes; Lewis acids; transmetalation; zirconocene coupling; OLEFIN POLYMERIZATION; PERFLUOROPHENYL DERIVATIVES; ZIRCONOCENE; ACTIVATION; SYSTEMS; ANTIAROMATICITY; 9-BORAFLUORENE; HYDROSILATION; DIBENZOBOROLE; COCATALYSTS;

D O I：

10.1002/anie.200900695

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zirconocene is the key: A new synthetic method, which utilizes zirconocene-mediated coupling of alkynes, has been developed for the preparation of a new class of highly Lewis acidic boroles (see scheme). Such compounds hold potential for applications in catalysis and the field of electron-deficient organic materials. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2835 / 2837

页数：3

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