A Broad Substrate-Scope Method for Fast, Efficient and Selective Hydrogen Peroxide-Epoxidation

被引：95
|
作者：
Garcia-Bosch, Isaac [1 ]
Ribas, Xavi [1 ]
Costas, Miquel [1 ]
机构：
[1] Fac Ciencies, Dept Quim, Girona 17071, Spain
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2009年 / 351卷 / 03期
关键词：
catalysis; chemoselectivity; epoxidation; hydrogen peroxide; manganese; ELECTRON-DEFICIENT OLEFINS; PERACETIC-ACID EPOXIDATION; MANGANESE COMPLEX; CATALYZED EPOXIDATIONS; CIS-DIHYDROXYLATION; ALKENE EPOXIDATION; TERMINAL OLEFINS; ACETIC-ACID; LIGANDS; OXIDATION;
D O I：
10.1002/adsc.200800650
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The efficient epoxidation of a broad range of olefins using hydrogen peroxide (H2O2) as the oxidant has been accomplished by a manganese catalyst that exhibits an uncommon chemoselectivity.
引用
收藏
页码：348 / 352
页数：5
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