Mono- and dinuclear platinum(II) complexes via single and double cycloplatinations of N′-(arylidene)benzohydrazides

被引：6

作者：

Rao, A. R. Balavardhana ^{[1
]}

Pal, Samudranil ^{[1
]}

机构：

[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2015年 / 797卷

关键词：

Cycloplatination; Benzoyl hydrazone; Mononuclear; Dinuclear; Crystal structures; REGIOSELECTIVE CYCLOMETALATION; PALLADIUM(II); IRIDIUM(III); THIOSEMICARBAZONES; CRYSTAL; LIGANDS; METALS;

D O I：

10.1016/j.jorganchem.2015.08.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Monocycloplatinated complexes [Pt(HLn)(PPh3)] were synthesized using [Pt(dmso)(2)Cl-2], N'-(arylidene) benzohydrazides (H3Ln, arylidene = 1-naphthylidene or 9-phenanthrylidene), NaOAc center dot 3H(2)O, and PPh3 in 1:1:1:2 mol ratio. The same reagents in 2:1:1:2 mol ratio provided the dicycloplatinated complexes [Pt-2(mu-L-n)(PPh3)(2)Cl]. All the complexes have been characterized by elemental analysis, X-ray crystallographic and spectroscopic measurements. X-ray structures reveal that (HLn)(2-) acts as pincer-like CNO-donor in [Pt(HLn)(PPh3)], while the dinucleating (L-n)(3-) behaves as pentadentate ligand and acts is CNO-donor to one metal centre and CN-donor to the second metal centre in [Pt-2(mu-L-n)(PPh3)(2)Cl]. The spectroscopic (IR, UV-Vis and NMR) features of both types of complexes are in agreement with their corresponding identities. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：96 / 100

页数：5

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