Kinetics of the thermal decomposition of poplar sawdust

被引:11
作者
Xiang, Yulin [1 ]
Xiang, Yuxiu [2 ]
Wang, Lipeng [1 ]
机构
[1] Yulin Univ, Coll Chem & Chem Engn, Yulin 719000, Shaanxi Provinc, Peoples R China
[2] Qiqihar Inst Engn, Dept Engn Management, Qiqihar, Heilongjiang Pr, Peoples R China
基金
中国国家自然科学基金;
关键词
Calorific value; isoconversional method; kinetic parameters; poplar sawdust; thermogravimetric analysis; THERMOGRAVIMETRIC ANALYSIS; BIOMASS; PYROLYSIS; WASTE; PARAMETERS; BLENDS; STRAW;
D O I
10.1080/15567036.2016.1212291
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In order to investigate the kinetic mechanism of thermal decomposition of poplar sawdust, the thermogravimetric experiments were performed using a thermogravimetric analyzer. The results showed that the activation energy varied from 17.64 kJ/mol to 161.14 kJ/mol. The pre-exponential factor values indicated empirical first-order reaction. The Gibbs free energy values varied from 127.88 kJ/mol to 223.55 kJ/mol, and the entropy changes were negative. The calorific value of the biomass was 19,482 kJ/kg.
引用
收藏
页码:213 / 218
页数:6
相关论文
共 13 条
[11]   Thermogravimetric Kinetic Analysis of the Pyrolysis of Rice Straw [J].
Kongkaew, Nithitorn ;
Pruksakit, Witchaya ;
Patumsawad, Suthum .
2015 INTERNATIONAL CONFERENCE ON ALTERNATIVE ENERGY IN DEVELOPING COUNTRIES AND EMERGING ECONOMIES, 2015, 79 :663-670
[12]   Influence of Chemical Treatment on Rice Straw Pyrolysis by TG-FTIR [J].
Sheng, Jiafeng ;
Ji, Dengxiang ;
Yu, Fengwen ;
Cui, Li ;
Zeng, Qingzhuo ;
Ai, Ning ;
Ji, Jianbing .
INTERNATIONAL CONFERENCE ON AGRICULTURAL AND BIOSYSTEM ENGINEERING (ABE 2014), 2014, 8 :30-34
[13]  
Xin Y., 2014, RES EXPLOR LAB, V7, P39