Kinetics of the thermal decomposition of poplar sawdust

被引:11
作者
Xiang, Yulin [1 ]
Xiang, Yuxiu [2 ]
Wang, Lipeng [1 ]
机构
[1] Yulin Univ, Coll Chem & Chem Engn, Yulin 719000, Shaanxi Provinc, Peoples R China
[2] Qiqihar Inst Engn, Dept Engn Management, Qiqihar, Heilongjiang Pr, Peoples R China
基金
中国国家自然科学基金;
关键词
Calorific value; isoconversional method; kinetic parameters; poplar sawdust; thermogravimetric analysis; THERMOGRAVIMETRIC ANALYSIS; BIOMASS; PYROLYSIS; WASTE; PARAMETERS; BLENDS; STRAW;
D O I
10.1080/15567036.2016.1212291
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In order to investigate the kinetic mechanism of thermal decomposition of poplar sawdust, the thermogravimetric experiments were performed using a thermogravimetric analyzer. The results showed that the activation energy varied from 17.64 kJ/mol to 161.14 kJ/mol. The pre-exponential factor values indicated empirical first-order reaction. The Gibbs free energy values varied from 127.88 kJ/mol to 223.55 kJ/mol, and the entropy changes were negative. The calorific value of the biomass was 19,482 kJ/kg.
引用
收藏
页码:213 / 218
页数:6
相关论文
共 13 条
[1]   Kinetics of the pyrolysis of arundo, sawdust, corn stover and switch grass biomass by thermogravimetric analysis using a multi-stage model [J].
Biney, Paul O. ;
Gyamerah, Michael ;
Shen, Jiacheng ;
Menezes, Bruna .
BIORESOURCE TECHNOLOGY, 2015, 179 :113-122
[2]   Thermogravimetric characteristics and kinetics analysis of oil cake and torrefied biomass blends [J].
Cao, Liang ;
Yuan, Xingzhong ;
Jiang, Longbo ;
Li, Changzhu ;
Xiao, Zhihua ;
Huang, Zhongliang ;
Chen, Xiaohong ;
Zeng, Guangming ;
Li, Hui .
FUEL, 2016, 175 :129-136
[3]   Kinetic parameters of red pepper waste as biomass to solid biofuel [J].
Domingos Maia, Amanda Alves ;
de Morais, Leandro Cardoso .
BIORESOURCE TECHNOLOGY, 2016, 204 :157-163
[4]   Investigation on the co-combustion of oil shale and municipal solid waste by using thermogravimetric analysis [J].
Fan, Yunlong ;
Yu, Zhaosheng ;
Fang, Shiwen ;
Lin, Yan ;
Lin, Yousheng ;
Liao, Yanfen ;
Ma, Xiaoqian .
ENERGY CONVERSION AND MANAGEMENT, 2016, 117 :367-374
[5]  
Gaparovie L., 2012, CHEM BIOCHEM ENG Q, V26, P45
[6]   Ethanol from lignocellulosic biomass: techno-economic performance in short-, middle- and long-term [J].
Hamelinck, CN ;
van Hooijdonk, G ;
Faaij, APC .
BIOMASS & BIOENERGY, 2005, 28 (04) :384-410
[7]   Pyrolysis kinetics of soybean straw using thermogravimetric analysis [J].
Huang, Xin ;
Cao, Jing-Pei ;
Zhao, Xiao-Yan ;
Wang, Jing-Xian ;
Fan, Xing ;
Zhao, Yun-Peng ;
Wei, Xian-Yong .
FUEL, 2016, 169 :93-98
[8]   A thermogravimetric analysis of the combustion kinetics of karanja (Pongamia pinnata) fruit hulls char [J].
Islam, Md Azharul ;
Auta, M. ;
Kabir, G. ;
Hameed, B. H. .
BIORESOURCE TECHNOLOGY, 2016, 200 :335-341
[9]   A comparative reactivity and kinetic study on the combustion of coal-biomass char blends [J].
Kastanaki, E ;
Vamvuka, D .
FUEL, 2006, 85 (09) :1186-1193
[10]   Investigation of Thermodynamic Parameters in the Thermal Decomposition of Plastic Waste-Waste Lube Oil Compounds [J].
Kim, Yong Sang ;
Kim, Young Seok ;
Kim, Sung Hyun .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2010, 44 (13) :5313-5317