Melt synthesis and characterization of complexed perovskite-oxides in the system of A2+(B2/5+B3/56+)O3 -: A3+(B3/5+B2/56+)O3

被引:5
作者
Ishigaki, Tadashi [1 ]
Nishimura, Eiichiro [1 ]
Seki, Kazumasa [1 ]
Watanabe, Tomoaki [1 ]
Yoshimura, Masahiro [1 ]
机构
[1] Tokyo Inst Technol, Mat & Struct Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
关键词
perovskite; synthesis; solidification; complex perovskite; melt synthesis;
D O I
10.1007/s10832-006-6709-2
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In order to synthesize various Perovskite ABO(3) type compounds and their solid solutions, we have applied a novel "melt synthesis technique" rather than conventional solid state reaction techniques. In the melt synthesis, the mixture of oxides or their precursors is melted in a short period of time (1-60 sec) by a strong light radiation in an arc imaging furnace. A spherical molten sample where multiple cations were mixed homogeneously was directly solidified on a copper hearth with a rapid cooling of 10(2) K/sec. Solid solutions based upon 1: 1 ordered Perovskite in the system of Sr(Li2/5W3/5)O-3-La(Li3/5W2/5)O-3 were synthesized in this technique.
引用
收藏
页码:885 / 889
页数:5
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