Decomposition kinetics of iron (III)-diclofenac compound

被引：16

作者：

Kobelnik, M. ^{[1
]}

Bernabe, Giseli Aparecida ^{[1
]}

Ribeiro, C. A. ^{[1
]}

Capela, J. M. V. ^{[1
]}

Fertonani, F. L. ^{[1
]}

机构：

[1] Univ Estadual Paulista, UNESP, Dept Quim Analit, Inst Quim Araraquara, Sao Paulo, SP, Brazil

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2009年 / 97卷 / 02期

关键词：

Iron(III)-diclofenac; Thermal decomposition; Non-isothermal; Activation energy; METAL-COMPLEXES; DICLOFENAC;

D O I：

10.1007/s10973-009-0336-5

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Non-isothermal decomposition of iron (III)-diclofenac anhydrous salt was investigated by thermogravimetry (TG) under different conditions in opened and closed alpha-alumina pans under nitrogen atmosphere. To estimate the activation energy of decomposition, the Capela and Ribeiro isoconversional method was applied. The results show that due to the lid cover different activation energies were obtained. From these curves a tendency can be seen where the plots maintain the same profile for closed lids and almost run parallel to each other. Independently of the different experimental conditions no remarkably different results have been obtained.

引用

页码：493 / 496

页数：4

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