3D metal-organic frameworks incorporating water-soluble tetra-p-sulfonatocalix[4]arene

被引：26
|
作者：
Liao, Wuping [1 ]
Liu, Ce [1 ]
Wang, Xiaofei [1 ]
Zhu, Guangshan [2 ]
Zhao, Xiaojun [2 ]
Zhang, Hongjie [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
来源：
CRYSTENGCOMM | 2009年 / 11卷 / 11期
基金：
中国国家自然科学基金;
关键词：
MOLECULAR CAPSULES; CROWN-ETHERS; COORDINATION; COMPLEXES; CONFINEMENT; ADSORPTION; HYDROGEN; BILAYER; SPHERES; DESIGN;
D O I：
10.1039/b908189e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Water-soluble tetra-p-sulfonatocalix[4]arene, acting as a four-connected node, bridges the rare earth cations into a 3D porous MOF in which 1D smaller circular hydrophilic channels and larger quadratic ones are lined up along the c axis and interconnected to each other by the calixarene cavities and other interstices.
引用
收藏
页码：2282 / 2284
页数：3
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