[Re(CO)3(bipy)(ClO4)]: Synthesis in a Proton-Donor Solvent, Crystal, and Molecular Structure

被引：3

作者：

Miroslavov, A. E. ^{[1
,2
]}

Sidorenko, G. V. ^{[1
]}

Tyupina, M. Yu. ^{[1
,2
]}

Gurzhiy, V. V. ^{[2
]}

机构：

[1] Khlopin Radium Inst, St Petersburg 194021, Russia

[2] St Petersburg State Univ, St Petersburg 199034, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2020年 / 90卷 / 12期

基金：

俄罗斯基础研究基金会;

关键词：

rhenium tricarbonyl complexes; bipyridine complexes; perchlorate complexes; single crystal X-ray diffraction analysis; TRICARBONYL COMPLEXES; RHENIUM; TECHNETIUM(I); LIGANDS;

D O I：

10.1134/S1070363220120178

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex [Re(CO)(3)(bipy)(ClO4)] (bipy = 2,2MODIFIER LETTER PRIME-bipyridine) was prepared by the reaction of [Re(CO)(3)(H2O,EtOH)(3)](ClO4) with bipy in aqueous ethanol, followed by crystallization from dichloromethane. The composition and structure of the complex were determined by single crystal X-ray diffraction analysis. The complex has a molecular octahedral structure with bidentate coordination of bipy and inner-sphere monodentate coordination of perchlorate ion in the fac-position to bipy. The complex was also characterized by IR and UV-visible absorption spectroscopy.

引用

页码：2333 / 2337

页数：5

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