NASICON type ordered mesoporous lithium-aluminum-titanium-phosphate as electrode materials for lithium-ion batteries

被引：27

作者：

Bhanja, Piyali ^{[1
]}

Senthil, Chenrayan ^{[2
]}

Patra, Astam Kumar ^{[1
]}

Sasidharan, Manickam ^{[2
]}

Bhaumik, Asim ^{[1
]}

机构：

[1] Indian Assoc Cultivat Sci, Dept Mat Sci, Kolkata 700032, India

[2] SRM Univ, SRM Res Inst, Madras 603203, Tamil Nadu, India

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2017年 / 240卷

关键词：

Mesoporous materials; Lithium-aluminum-titanium-phosphate; Lithium ion battery; Anode material; Discharge-charge performances; TRANSITION-METAL PHOSPHATES; SENSITIZED SOLAR-CELLS; LONG CYCLE LIFE; MOLECULAR-SIEVES; AIR BATTERY; SOLID-ELECTROLYTE; CATHODE; CARBON; CONDUCTIVITY; CRYSTAL;

D O I：

10.1016/j.micromeso.2016.11.005

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

An ordered 2D-hexagonal mesoporous Lithium-Aluminum-Titanium-Phosphate (LATP-1) material has been synthesized by using cetyltrimethylammonium bromide (CTAB) as the structure directing agent (SDA) thorough hydrothermal route. After acid-ethanol extraction of the as-synthesized LATP-1 material, the extracted white solid product has been characterized thoroughly using small and wide angle powder X-ray diffraction (XRD), nitrogen adsorption/desorption analysis, X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FTIR) spectroscopy, field emission scanning electron microscopy (FE-SEM), Ultra-high resolution transmission electron microscopy (UHR-TEM) and thermogravimetric analysis (TGA). Elemental analysis revealed 2.53% Li, 2.02% Al, 4.84% Ti, 28.16% P, 62.44% O in the mesoporous LATP-1 material. The template-extracted LATP-1 material has been employed as anode and cathode materials for lithium ion batteries: as an anode material, the LATP-1 electrode exhibits stable discharge-charge performances with delivered capacity of 121 mAh.g(-1) and 117 mAh.g(-1), respectively and a high coulombic efficiency. (C) 2016 Elsevier Inc. All rights reserved.

引用

页码：57 / 64

页数：8

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