Degradation of the ruthenium-based metathesis catalyst [RuCl2(CHPh)(H2IPr)(PCy3)] with primary alcohols

被引：47

作者：

Banti, D ^{[1
]}

Mol, JC ^{[1
]}

机构：

[1] Univ Amsterdam, Inst Mol Chem, Fac Sci, NL-1018 WV Amsterdam, Netherlands

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 20期

关键词：

metathesis; isopropylidene ligand; hydride; isomerization; hydrogenation;

D O I：

10.1016/j.jorganchem.2004.07.033

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new ruthenium hydride species, showing high catalytic isomerization and hydrogenation properties, was isolated via a ligand exchange reaction. The same species was also present in the mixture of degradation products of the monophosphinic complex RuCl(CO)(PCy)(3)(IPr)CH(Ph), 3, after reaction with alcohols under basic conditions. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：3113 / 3116

页数：4

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