A versatile method for producing functionalized cellulose nanofibers and their application

被引:107
作者
Huang, Pei [1 ]
Zhao, Yang [1 ]
Kuga, Shigenori [1 ]
Wu, Min [1 ]
Huang, Yong [1 ]
机构
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100190, Peoples R China
基金
中国国家自然科学基金;
关键词
NANOCOMPOSITES; ESTERIFICATION; BIOCOMPOSITES; COMPOSITES; FIBERS;
D O I
10.1039/c5nr08179c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A facile method was developed to produce functionalized cellulose nanofibers in one step by ball milling. Through the synergy of mechanical and chemical actions, the produced cellulose nanofibers are ca. 20 nm wide and several micrometers long, with surface properties tailored by choice of modifying reagent. Modified by succinic anhydride, a cellulose nanofiber shows enhanced hydrophilicity, can be readily dispersed in water or DMSO, and gives a zeta potential of -38.7 mV due to carboxyl groups on the surface. Modified by dodecyl succinic anhydride, a cellulose nanofiber has excellent dispersibility in o-xylene and good compatibility with polyethylene. The polyethylene-cellulose nanofiber composite presents overall enhancement of mechanical properties. This method opens a new way to the production of functionalized cellulose nanofibers.
引用
收藏
页码:3753 / 3759
页数:7
相关论文
共 22 条
[1]   Biocomposites from wheat straw nanofibers: Morphology, thermal and mechanical properties [J].
Alemdar, Ayse ;
Sain, Mohini .
COMPOSITES SCIENCE AND TECHNOLOGY, 2008, 68 (02) :557-565
[2]  
[Anonymous], 2011, ANGEW CHEM, DOI DOI 10.1021/ACSSUSCHEMENG.9B00224
[3]  
Cavaille J., 2000, U.S. Patent, Patent No. [6,117,545, 6117545]
[4]   Fluorescently labeled cellulose nanocrystals for bioimaging applications [J].
Dong, Shuping ;
Roman, Maren .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (45) :13810-+
[5]   Review: current international research into cellulose nanofibres and nanocomposites [J].
Eichhorn, S. J. ;
Dufresne, A. ;
Aranguren, M. ;
Marcovich, N. E. ;
Capadona, J. R. ;
Rowan, S. J. ;
Weder, C. ;
Thielemans, W. ;
Roman, M. ;
Renneckar, S. ;
Gindl, W. ;
Veigel, S. ;
Keckes, J. ;
Yano, H. ;
Abe, K. ;
Nogi, M. ;
Nakagaito, A. N. ;
Mangalam, A. ;
Simonsen, J. ;
Benight, A. S. ;
Bismarck, A. ;
Berglund, L. A. ;
Peijs, T. .
JOURNAL OF MATERIALS SCIENCE, 2010, 45 (01) :1-33
[6]   Cellulose nanowhiskers: promising materials for advanced applications [J].
Eichhorn, Stephen J. .
SOFT MATTER, 2011, 7 (02) :303-315
[7]   Cellulose swelling by aprotic and protic solvents: What are the similarities and differences? [J].
Fidale, Ludmila C. ;
Ruiz, Naiara ;
Heinze, Thomas ;
El Seoud, Omar A. .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2008, 209 (12) :1240-1254
[8]   Transparent and High Gas Barrier Films of Cellulose Nanofibers Prepared by TEMPO-Mediated Oxidation [J].
Fukuzumi, Hayaka ;
Saito, Tsuguyuki ;
Wata, Tadahisa ;
Kumamoto, Yoshiaki ;
Isogai, Akira .
BIOMACROMOLECULES, 2009, 10 (01) :162-165
[9]   All-cellulose nanocomposite [J].
Gindl, W ;
Keckes, J .
POLYMER, 2005, 46 (23) :10221-10225
[10]   Biomolecular modification of hierarchical cellulose fibers through titania nanocoating [J].
Huang, Jianguo ;
Ichinose, Izumi ;
Kunitake, Toyoki .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (18) :2883-2886