Pentamethylcyclopentadienyl rhodium and iridium complexes containing oxinato ligands

被引：18

作者：

Thai, Trieu-Tien ^{[1
]}

Therrien, Bruno ^{[1
]}

Suess-Fink, Georg ^{[1
]}

机构：

[1] Univ Neuchatel, Inst Chim, CH-2009 Neuchatel, Switzerland

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2009年 / 12卷 / 08期

基金：

瑞士国家科学基金会;

关键词：

Rhodium; Iridium; Pentamethylcyclopentadienyl; Oxinato;

D O I：

10.1016/j.inoche.2009.06.023

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The neutral chloror complexes [(eta(5)-C5Me5)M(eta(2)-NC9H6O)Cl] as well as the cationic aqua complexes [(eta 5-C5Me5)M(eta(2) -NC9H6O)(H2O)](+) (M = Rh, Ir) have been synthesized from the reaction of the dinuclear precursors [eta(5)-C5Me5)MCl2](2) and 8-hydroxyquinoline. The single crystal X-ray structure analysis of [(eta(5)-C5Me5)Ir(eta(2)-NC9H6O)Cl] reveals for these complexes a piano-stool arrangement with the aromatic ligand, the chelating oxinato ligand and the terminal chloro or aqua ligand surrounding the metal center in a pseudo-tetrahedral fashion. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：806 / 807

页数：2

共 50 条

[41] Variable structural bonding modes and antibacterial studies of thiosemicarbazone ligands of ruthenium, rhodium, and iridium metal complexes
Shadap, Lathewdeipor
Banothu, Venkanna
Adepally, Uma
Adhikari, Sanjay
Kollipara, Mohan Rao
JOURNAL OF COORDINATION CHEMISTRY, 2020, 73 (01) : 175 - 187
[42] Synthesis and characterization of half-sandwich iridium(III) and rhodium(III) complexes bearing organochalcogen ligands
Jia, Wei-Guo
Huang, Yuan-Biao
Jin, Guo-Xin
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (21) : 3376 - 3380
[43] The effects of metals and ligands on the oxidation of n-octane using iridium and rhodium "PNP" aminodiphosphine complexes
Naicker, Dunesha
Alapour, Saba
Friedrich, Holger B.
JOURNAL OF CHEMICAL RESEARCH, 2021, 45 (3-4) : 282 - 289
[44] Catalytic redox isomerization of allylic alcohols with rhodium and iridium complexes with ferrocene phosphine-thioether ligands
Titova, Ekaterina M.
Rahaman, S. M. Wahidur
Shubina, Elena S.
Poli, Rinaldo
Belkova, Natalia V.
Manoury, Eric
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2017, 426 : 376 - 380
[45] Synthesis and structure of rhodium complexes containing extended terpyridyl ligands
Paul, J
Spey, S
Adams, H
Thomas, JA
INORGANICA CHIMICA ACTA, 2004, 357 (10) : 2827 - 2832
[46] Stepwise formation of quasi-octahedral macrocyclic complexes of rhodium(III) and iridium(III) bearing a pentamethylcyclopentadienyl group
Yamamotoa, Y
Suzuki, H
Tajima, N
Tatsumi, K
CHEMISTRY-A EUROPEAN JOURNAL, 2002, 8 (02) : 372 - 379
[47] Towards rhodium and iridium complexes containing the secondary phosphane ligand tBU2PH
Boettcher, Hans-Christian
Graf, Marion
Karaghiosoff, Konstantin
Mayer, Peter
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2007, 633 (13-14): : 2374 - 2379
[48] Rhodium complexes containing bidentate imidazolyl ligands: synthesis and structure
Elgafi, S
Field, LD
Messerle, BA
Turner, P
Hambley, TW
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 588 (01) : 69 - 77
[49] Rhodium and Iridium Complexes with α-Diketimine Ligands: Oxidative Addition of H2 and O2
Penner, Anna
Braun, Thomas
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2011, (16) : 2579 - 2587
[50] Ruthenium, rhodium and iridium complexes containing pyrimidine based thienyl pyrazoles: Synthesis and antibacterial studies
Lapasam, Agreeda
Mawnai, Ibaniewkor L.
Banothu, Venkanna
Kaminsky, Werner
Kollipara, Mohan Rao
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2020, 911

← 1 2 3 4 5 →