Pentamethylcyclopentadienyl rhodium and iridium complexes containing oxinato ligands

被引：18
|
作者：
Thai, Trieu-Tien [1 ]
Therrien, Bruno [1 ]
Suess-Fink, Georg [1 ]
机构：
[1] Univ Neuchatel, Inst Chim, CH-2009 Neuchatel, Switzerland
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2009年 / 12卷 / 08期
基金：
瑞士国家科学基金会;
关键词：
Rhodium; Iridium; Pentamethylcyclopentadienyl; Oxinato;
D O I：
10.1016/j.inoche.2009.06.023
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The neutral chloror complexes [(eta(5)-C5Me5)M(eta(2)-NC9H6O)Cl] as well as the cationic aqua complexes [(eta 5-C5Me5)M(eta(2) -NC9H6O)(H2O)](+) (M = Rh, Ir) have been synthesized from the reaction of the dinuclear precursors [eta(5)-C5Me5)MCl2](2) and 8-hydroxyquinoline. The single crystal X-ray structure analysis of [(eta(5)-C5Me5)Ir(eta(2)-NC9H6O)Cl] reveals for these complexes a piano-stool arrangement with the aromatic ligand, the chelating oxinato ligand and the terminal chloro or aqua ligand surrounding the metal center in a pseudo-tetrahedral fashion. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：806 / 807
页数：2
相关论文
共 50 条
  • [21] Synthesis, cytotoxicity and antibacterial activities of ruthenium, rhodium and iridium metal complexes containing diazafluorene functionalized ligands
    Nongpiur, Carley Giffert L.
    Verma, Akalesh Kumar
    Ghate, Mayur Mohan
    Poluri, Krishna Mohan
    Kaminsky, Werner
    Kollipara, Mohan Rao
    JOURNAL OF MOLECULAR STRUCTURE, 2023, 1285
  • [22] Metal complexes of biologically important ligands.: XCV -: η5-pentamethylcyclopentadienyl rhodium, iridium, η6-benzene ruthenium, and phosphine palladium complexes of proline methylester and proline amide
    Hoffmuller, W
    Polborn, K
    Knizek, J
    Noth, H
    Beck, W
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1997, 623 (12): : 1903 - 1911
  • [23] Synthesis and characterization of new pentamethylcyclopentadienyl iridium hydride complexes
    Talavera, Maria
    Bolano, Sandra
    Bravo, Jorge
    Castro, Jesus
    Garcia-Fontan, Soledad
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2012, 715 : 113 - 118
  • [24] Cellular Selectivity and Biological Impact of Cytotoxic Rhodium(III) and Iridium(III) Complexes Containing Methyl-Substituted Phenanthroline Ligands
    Geldmacher, Yvonne
    Kitanovic, Igor
    Alborzinia, Hamed
    Bergerhoff, Katharina
    Rubbiani, Riccardo
    Wefelmeier, Pascal
    Prokop, Aram
    Gust, Ronald
    Ott, Ingo
    Woelfl, Stefan
    Sheldrick, William S.
    CHEMMEDCHEM, 2011, 6 (03) : 429 - 439
  • [25] Hydrogenation of heteroaromatic nitrogen compounds catalyzed by rhodium and iridium systems containing diphosphine ligands
    Merlín Rosales
    Regina Vallejo
    Luis Jhonatan Bastidas
    Beatriz González
    Angel González
    Reaction Kinetics and Catalysis Letters, 2007, 92 : 99 - 104
  • [26] Syntheses, spectral and structural studies of Schiff base complexes of η5-pentamethylcyclopentadienyl rhodium and iridium
    Govindaswamy, P
    Mozharivskyj, YA
    Kollipara, MR
    POLYHEDRON, 2005, 24 (13) : 1710 - 1716
  • [27] INTRAZEOLITE ORGANOMETALLICS - PENTAMETHYLCYCLOPENTADIENYL RHODIUM COMPLEXES
    BALKUS, KJ
    NOWINSKA, K
    MICROPOROUS MATERIALS, 1995, 3 (06): : 665 - 686
  • [28] Chiral half-sandwich pentamethylcyclopentadienyl rhodium(III) and iridium(III) complexes with Schiff bases from salicylaldehyde and α-amino acid esters [1]
    Boehm, Andreas
    Brunner, Henri
    Beck, Wolfgang
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2008, 634 (02): : 274 - 278
  • [29] Hydrogenation of heteroaromatic nitrogen compounds catalyzed by rhodium and iridium systems containing diphosphine ligands
    Rosales, Merlin
    Vallejo, Regina
    Bastidas, Luis Jhonatan
    Gonzalez, Beatriz
    Gonzalez, Angel
    REACTION KINETICS AND CATALYSIS LETTERS, 2007, 92 (01): : 99 - 104
  • [30] Mono- and dinuclear rhodium and iridium complexes with chiral phospholanes as ligands
    Krüger, P
    Werner, H
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (03) : 481 - 491
12345