Compound of (NH4)2SnP4O13 with high proton conductivity in both dry and humid atmospheres as electrolyte for intermediate temperature fuel cells

被引：3
作者：
Wang, Haibo [1 ,2 ,3 ]
Tealdi, Cristina [2 ]
Huang, Kelong [3 ]
Stimming, Ulrich [2 ]
Chen, Liquan [3 ,4 ]
机构：
[1] Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
[2] Tech Univ Munich, Dept Phys E19, D-85748 Garching, Germany
[3] Cent S Univ, Sch Chem & Chem Engn, Changsha 410083, Peoples R China
[4] Chinese Acad Sci, Inst Phys, Beijing 100080, Peoples R China
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2009年 / 485卷 / 1-2期
关键词：
Phosphate; Compound; Conductivity; Intermediate temperature fuel cells; POLYPHOSPHATE COMPOSITE;
D O I：
10.1016/j.jallcom.2009.05.148
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this paper, a new proton-conductive compound of (NH4)(2)SnP4O13 was synthesized by a simple solid state method. X-ray diffraction, scanning electronic microscopy and thermal gravimetric analysis investigation were performed on this compound. The conductivity of (NH4)(2)SnP4O13 was measured by impendence spectroscopy with the temperature range of 125-275 degrees C under different atmospheres. Maximum conductivities of 13.8 mS cm-(1) at 275 degrees C under dry H-2 and 35.5 mS cm(-1) at 225 degrees C under wet H-2 respectively were obtained. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：L28 / L30
页数：3
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