Superior mechanical properties of poly vinyl alcohol-assisted ZnO nanoparticle reinforced epoxy composites

被引:23
作者
Haider, Sudipta [1 ]
Prasad, Tankeshwar [1 ]
Khan, Nazrul Islam [1 ]
Goyat, M. S. [2 ]
Chauhan, Sri Ram [1 ]
机构
[1] Natl Inst Technol Silchar, Dept Mech Engn, Silchar 788010, Assam, India
[2] Univ Petr & Energy Studies, Coll Engn Studies, Dept Phys, Dehra Dun 248007, Uttarakhand, India
关键词
ZnO nanoparticles; Fracture toughness; Thermal stability; Mechanical testing; Sol-gel method; GLASS-TRANSITION; NANOCOMPOSITES; DISPERSION; GROWTH; INTERPHASE; STRENGTH; OXIDE; SIZE;
D O I
10.1016/j.matchemphys.2016.12.055
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This work demonstrates the effect of poly vinyl alcohol modified ZnO nanoparticles on thermal and mechanical properties of epoxy nanocomposites. Modified ZnO nanoparticles with controlled particle size were successfully synthesized by sol-gel method. The surface modification of nanoparticles was confirmed by FT-IR, EDX and TGA analysis. Epoxy nanocomposites were prepared using different wt% (0 3 wt%) of unmodified and modified ZnO nanoparticles. A significant improvement in T-g was achieved for synthesized epoxy nanocomposites. The dispersion and interfacial interactions between unmodified (ZN) and PVA modified ZnO (PZN) with the epoxy matrix were investigated by morphological study of fractured surface of epoxy nanocomposites. The improvement in mechanical performance of PVAassisted ZnO nanoparticle reinforced epoxy composites was found superior at 2 wt% of particle concentration. The maximum enhancement in mechanical properties such as tensile strength, tensile modulus, compressive strength, flexural strength and flexural modulus was similar to 24, 47, 48, 44 and 77% respectively with respect to that of neat epoxy system. We have exposed the potential of the PVAassisted ZnO nanoparticle as good choice of reinforcement for composite industries. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:198 / 209
页数:12
相关论文
共 54 条
[51]   Effect of Surface Functional Modification of Nano-Alumina Particles on Thermal and Mechanical Properties of Epoxy Nanocomposites [J].
Yu, Zhi-Qiang ;
You, Shu-Li ;
Yang, Zhen-Guo ;
Baier, Horst .
ADVANCED COMPOSITE MATERIALS, 2011, 20 (05) :487-502
[52]   Property improvements of in situ epoxy nanocomposites with reduced interparticle distance at high nanosilica content [J].
Zhang, H ;
Zhang, Z ;
Friedrich, K ;
Eger, C .
ACTA MATERIALIA, 2006, 54 (07) :1833-1842
[53]   Controllable growth of ZnO microcrystals by a capping-molecule-assisted hydrothermal process [J].
Zhang, H ;
Yang, DR ;
Li, DS ;
Ma, XY ;
Li, SZ ;
Que, DL .
CRYSTAL GROWTH & DESIGN, 2005, 5 (02) :547-550
[54]   Enhanced mechanical properties of epoxy nanocomposites based on graphite oxide with amine-rich surface [J].
Zhou, Ya ;
Li, Le ;
Chen, Yang ;
Zou, Huawei ;
Liang, Mei .
RSC ADVANCES, 2015, 5 (119) :98472-98481