Performance of a co-electrodeposited Pt-Ru electrode for the electro-oxidation of ethanol studied by in situ FTIR spectroscopy

被引:66
作者
Souza, JPI [1 ]
Rabelo, FJB [1 ]
deMoraes, IR [1 ]
Nart, FC [1 ]
机构
[1] UNIV SAO PAULO, INST QUIM, BR-13560970 SAO CARLOS, BRAZIL
基金
巴西圣保罗研究基金会;
关键词
electrocatalysis; ethanol; platinum; ruthenium;
D O I
10.1016/S0022-0728(96)01019-4
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The ethanol electro-oxidation on a co-electrodeposited Pt-Ru catalyst was studied by in situ FTIR spectroscopy. In contrast with the formation of the known acetaldehyde, acetic acid and carbon dioxide reaction products on a Pt catalyst, on the prepared Pt-Ru electrode only carbon dioxide was detected under the same experimental conditions.
引用
收藏
页码:17 / 20
页数:4
相关论文
共 16 条
[1]   INTERMEDIATES AND PRODUCTS OF ETHANOL OXIDATION ON PLATINUM IN ACID-SOLUTION [J].
BITTINSCATTANEO, B ;
WILHELM, S ;
CATTANEO, E ;
BUSCHMANN, HW ;
VIELSTICH, W .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1988, 92 (11) :1210-1218
[2]   ELECTROOXIDATION PATHWAYS OF SIMPLE ALCOHOLS AT PLATINUM IN PURE NONAQUEOUS AND CONCENTRATED AQUEOUS ENVIRONMENTS AS STUDIED BY REAL-TIME FTIR SPECTROSCOPY [J].
GAO, P ;
CHANG, SC ;
ZHOU, ZH ;
WEAVER, MJ .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1989, 272 (1-2) :161-178
[3]   ELECTROOXIDATION OF SMALL ORGANIC-MOLECULES ON WELL-CHARACTERIZED PT-RU ALLOYS [J].
GASTEIGER, HA ;
MARKOVIC, N ;
ROSS, PN ;
CAIRNS, EJ .
ELECTROCHIMICA ACTA, 1994, 39 (11-12) :1825-1832
[4]   CO ELECTROOXIDATION ON WELL-CHARACTERIZED PT-RU ALLOYS [J].
GASTEIGER, HA ;
MARKOVIC, N ;
ROSS, PN ;
CAIRNS, EJ .
JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (02) :617-625
[5]   METHANOL ELECTROOXIDATION ON WELL-CHARACTERIZED PT-RN ALLOYS [J].
GASTEIGER, HA ;
MARKOVIC, N ;
ROSS, PN ;
CAIRNS, EJ .
JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (46) :12020-12029
[6]   ELECTROCATALYTIC OXIDATION OF METHANOL AND ETHANOL - A COMPARISON OF PLATINUM-TIN AND PLATINUM RUTHENIUM CATALYST PARTICLES IN A CONDUCTING POLYANILINE MATRIX [J].
HABLE, CT ;
WRIGHTON, MS .
LANGMUIR, 1993, 9 (11) :3284-3290
[7]   A KINETIC, ANALYSIS OF THE ELECTROOXIDATION OF ETHANOL AT A PLATINUM-ELECTRODE IN ACID-MEDIUM [J].
HITMI, H ;
BELGSIR, EM ;
LEGER, JM ;
LAMY, C ;
LEZNA, RO .
ELECTROCHIMICA ACTA, 1994, 39 (03) :407-415
[8]   A DEMS AND FTIR SPECTROSCOPIC INVESTIGATION OF ADSORBED ETHANOL ON POLYCRYSTALLINE PLATINUM [J].
IWASITA, T ;
PASTOR, E .
ELECTROCHIMICA ACTA, 1994, 39 (04) :531-537
[9]   A SNIFTIRS STUDY OF ETHANOL OXIDATION ON PLATINUM [J].
IWASITA, T ;
RASCH, B ;
CATTANEO, E ;
VIELSTICH, W .
ELECTROCHIMICA ACTA, 1989, 34 (08) :1073-1079
[10]   REAL-TIME FTIR SPECTROSCOPY AS AN ELECTROCHEMICAL MECHANISTIC PROBE - ELECTROOXIDATION OF ETHANOL AND RELATED SPECIES ON WELL-DEFINED PT(111) SURFACES [J].
LEUNG, LWH ;
CHANG, SC ;
WEAVER, MJ .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1989, 266 (02) :317-336