Triangular halogen-halogen-halogen interactions as a cohesive force in the structures of trihalomesitylenes

被引：172
|
作者：
Bosch, E [1 ]
Barnes, CL
机构：
[1] SW Missouri State Univ, Dept Chem, Springfield, MO 65804 USA
[2] Univ Missouri, Dept Chem, Columbia, MO 65211 USA
来源：
CRYSTAL GROWTH & DESIGN | 2002年 / 2卷 / 04期
关键词：
D O I：
10.1021/cg025517w
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The structures and molecular packing of tribromo- and triiodomesitylene are reported and compared to that of trichloromesitylene. Attractive triangular X-3 interactions dominate the molecular packing in all three structures. The nonspherical atomic charge distribution on the halogens results in the formation donor-acceptor interactions in which each halogen atom is simultaneously a donor and an acceptor. These triangular X-3 (X = Br or I) interactions result in the formation of 2-dimensional sheetlike structures.
引用
收藏
页码：299 / 302
页数：4
相关论文
共 50 条
  • [41] A 2D Polychloride Network Held Together by Halogen-Halogen Interactions
    Brueckner, Robin
    Haller, Heike
    Steinhauer, Simon
    Mueller, Carsten
    Riedel, Sebastian
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (51) : 15579 - 15583
  • [42] Halogen ... phenyl supramolecular interactions in the solid state: hydrogen versus halogen bonding and directionality
    Mooibroek, Tiddo J.
    Gamez, Patrick
    CRYSTENGCOMM, 2013, 15 (09): : 1802 - 1805
  • [43] Hydrogen bonds chains supported by halogen-halogen interactions in di- and trihaloimidazoles
    Rajewski, Kacper W.
    Andrzejewski, Michal
    Marciniak, Jedrzej
    Katrusiak, Andrzej
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2015, 71 : S453 - S453
  • [44] Halogen•••Halogen interactions in 2D coordination polymers impact the Sorption behavior
    Mir, Mohammad Hedayetullah
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2017, 73 : C199 - C199
  • [45] Isostructurality, polymorphism and mechanical properties of some hexahalogenated benzenes:: The nature of halogen•••halogen interactions
    Reddy, CM
    Kirchner, MT
    Gundakaram, RC
    Padmanabhan, KA
    Desiraju, GR
    CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (08) : 2222 - 2234
  • [46] Using halogen•••halogen interactions to direct noncentrosymmetric crystal packing in dipolar organic molecules
    Saha, Binoy K.
    Nangia, Ashwini
    Nicoud, Jean-Francois
    CRYSTAL GROWTH & DESIGN, 2006, 6 (06) : 1278 - 1281
  • [47] Heteroleptic Zn(II)-Pentaiodobenzoate Complexes: Structures and Features of Halogen-Halogen Non-Covalent Interactions in Solid State
    Bondarenko, Mikhail A.
    Novikov, Alexander S.
    Sokolov, Maxim N.
    Adonin, Sergey A.
    INORGANICS, 2022, 10 (10)
  • [48] Refinement of OPLS force fields for halogen bonding and interactions with carbon surfaces
    Jorgensen, William L.
    Schyman, Patric
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [49] Cooperativity of hydrogen and halogen bond interactions
    Grabowski, Slawomir J.
    THEORETICAL CHEMISTRY ACCOUNTS, 2013, 132 (04)
  • [50] Intermolecular interactions involving halogen substituents
    Csoregh, I.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2000, 56 : S13 - S13
12345