Triangular halogen-halogen-halogen interactions as a cohesive force in the structures of trihalomesitylenes

被引：172
|
作者：
Bosch, E [1 ]
Barnes, CL
机构：
[1] SW Missouri State Univ, Dept Chem, Springfield, MO 65804 USA
[2] Univ Missouri, Dept Chem, Columbia, MO 65211 USA
来源：
CRYSTAL GROWTH & DESIGN | 2002年 / 2卷 / 04期
关键词：
D O I：
10.1021/cg025517w
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The structures and molecular packing of tribromo- and triiodomesitylene are reported and compared to that of trichloromesitylene. Attractive triangular X-3 interactions dominate the molecular packing in all three structures. The nonspherical atomic charge distribution on the halogens results in the formation donor-acceptor interactions in which each halogen atom is simultaneously a donor and an acceptor. These triangular X-3 (X = Br or I) interactions result in the formation of 2-dimensional sheetlike structures.
引用
收藏
页码：299 / 302
页数：4
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