The first synthesis of nitro-substituted cyclopropanes and spiropentanes via oxidation of the corresponding amino derivatives

被引：7
作者：
Volkova, Yuliya A. [1 ]
Ivanova, Olga A. [1 ]
Budynina, Ekaterina M. [1 ]
Revunov, Eugene V. [1 ]
Averina, Elena B. [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
来源：
TETRAHEDRON LETTERS | 2009年 / 50卷 / 23期
基金：
俄罗斯基础研究基金会;
关键词：
Cyclopropanes; Oxidation; Nitro-compounds; Dimethyldioxirane; DIAZO-COMPOUNDS; OZONATION; NITROCYCLOPROPANES; 3-(TRANS-2-NITROCYCLOPROPYL)ALANINE; NITROOLEFINS; GENERATION; ESTERS;
D O I：
10.1016/j.tetlet.2009.03.165
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel approach to nitro-substituted cyclopropanes and spiropentanes via oxidation of the corresponding amines with dimethyldioxirane is reported. The method is used successfully for the preparation of a series of nitrocyclopropanes as well as for the first synthesis of 4,4-dinitrospirol[2.2]pentane. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2793 / 2796
页数：4
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