The SERS of glycine anhydride on positive silver colloids

被引:0
|
作者
Si Min-zhen [1 ]
Zi Xing-fa
Wu Rong-guo
Zhang Peng-xiang
机构
[1] Chuxiong Teachers Coll, Dept Phys & Elect Sci, Chuxiong 675000, Peoples R China
[2] Chuxiong Environm Monitoring Stn, Chuxiong 675000, Peoples R China
[3] Kunming Univ Sci & Technol, IAMPE, Kunming 651000, Peoples R China
关键词
glycine anhydride; positive silver colloid; Raman spectrum; SERS; adsorption; B3LYP/6-31g(d);
D O I
暂无
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
The Raman spectrum and SERS of glycine anhydride in acidic and basic media on positive silver colloids were recorded. Calculations of the vibration frequencies were performed for glycine anhydride by B3LYP at 6-31g(d) level. The assignment of Raman spectrum and SERS of glycine anhydride in acidic media were obtained with the help of calculation. It was found that the glycine anhydride is physically adsorbed on the surface of silver. The SERS of glycine anhydride is very different in acidic media from that in basic media. This seems to mean that the geometry of glycine anhydride on positive silver colloid in basic media has changed.
引用
收藏
页码:1472 / 1475
页数:4
相关论文
共 17 条
  • [1] CREIGHTON JA, 1988, ADV SPECTROSC, V19, P37
  • [2] GALINA MC, 2001, J CHEM PHYS, V115, P1340
  • [3] A TEST OF SURFACE SELECTION-RULES FOR SURFACE-ENHANCED RAMAN-SCATTERING - THE ORIENTATION OF ADSORBED BENZENE AND MONOSUBSTITUTED BENZENES ON GOLD
    GAO, XP
    DAVIES, JP
    WEAVER, MJ
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (17): : 6858 - 6864
  • [4] MAREK B, 2002, INT J QUANTUM CHEM, V90, P689
  • [5] Mario T., 1998, VIB SPECTROSC, V16, P35
  • [6] MASATOMO A, 1974, SPECTROCHIM ACTA, V30, P1147
  • [7] MISRA TN, 2000, SAT M ICORS 2000 P I, P211
  • [8] Ogawa H, 1999, J PHYS ORG CHEM, V12, P354, DOI 10.1002/(SICI)1099-1395(199904)12:4<354::AID-POC157>3.0.CO
  • [9] 2-D
  • [10] [司民真 Si Minzhen], 2002, [光散射学报, Chinese Journal of Light Scattering], V14, P69