Clathration effects on the interpenetration in the 2D (4,4) coordination polymer {[Fe(4,4′-bipy)(dca)2]•bt}

被引：12

作者：

Gaspar, AB

Muñoz, MC

Real, JA

机构：

[1] Univ Valencia, Fac Quim, Inst Ciencia Mol, Dept Quim Inorgan, E-46100 Valencia, Spain

[2] Univ Politecn Valencia, Dept Fis Aplicada, Valencia 46022, Spain

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 06期

关键词：

crystal structures; iron complexes; coordination polymer complexes; self-assembling; inclusion chemistry;

D O I：

10.1016/j.inoche.2004.05.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel 2D polymer, {[Fe(4,4'-bipy)(dca)(2)] - bt}, (dca = dicyanamide, 4,4'-bipy = 4,4'-bipyridine and bt = 2,2'-bithiazoline) has been synthesized and characterized by X-ray crystallography. The structure reveals the formation of 2D (4,4) networks and intercalated bt uncoordinated ligands. (C) 2004 Elsevier B.V. All rights reserved.

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页码：815 / 817

页数：3

相关论文

共 12 条

[1] Structure and magnetism of coordination polymers containing dicyanamide and tricyanomethanide [J].

Batten, SR ;

Murray, KS .

COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :103-130

[2] Coexisting covalent and non-covalent planar networks in the crystal structures of {[M(bipy)2(NO3)2]•arene}n (M = Ni, 1; Co, 2; arene = chlorobenzene, o-dichlorobenzene, benzene, nitrobenzene, toluene or anisole) [J].

Biradha, K ;

Mondal, A ;

Moulton, B ;

Zaworotko, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (21) :3837-3844

[3] PREPARATION, CLATHRATION ABILITY, AND CATALYSIS OF A 2-DIMENSIONAL SQUARE NETWORK MATERIAL COMPOSED OF CADMIUM(II) AND 4,4'-BIPYRIDINE [J].

FUJITA, M ;

KWON, YJ ;

WASHIZU, S ;

OGURA, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (03) :1151-1152

[4] A NEW TYPE OF INTERPENETRATION INVOLVING ENMESHED INDEPENDENT SQUARE GRID SHEETS - THE STRUCTURE OF DIAQUABIS-(4,4'-BIPYRIDINE)ZINC HEXAFLUOROSILICATE [J].

GABLE, RW ;

HOSKINS, BF ;

ROBSON, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (23) :1677-1678

[5] Metal-organic frameworks [J].

James, SL .

CHEMICAL SOCIETY REVIEWS, 2003, 32 (05) :276-288

[6] Engineering coordination polymers towards applications [J].

Janiak, C .

DALTON TRANSACTIONS, 2003, (14) :2781-2804

[7] Syntheses, crystal structures, and magnetic properties of first row transition metal coordination polymers containing dicyanamide and 4,4′-bipyridine [J].

Jensen, P ;

Batten, SR ;

Moubaraki, B ;

Murray, KS .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (19) :3712-3722

[8] Structural analysis and magnetic properties of the 1D [Fe(dca)2bipy(H2O)]•1/2H2O and the 3D [Ni(dca)2bipy] (dca = dicyanamide; bipy=4,4′-bipyridine) [J].

Martín, S ;

Barandika, MG ;

Ezpeleta, JM ;

Cortés, R ;

de Larramendi, JIR ;

Lezama, L ;

Rojo, T .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (22) :4275-4280

[9] Mass effect on the equienergetic high-spin/low-spin states of spin-crossover in 4,4′-bipyridine-bridged iron(II) polymeric compounds:: Synthesis, structure, and magnetic, Mossbauer, and theoretical studies [J].

Molíner, N ;

Muñoz, MC ;

Létard, S ;

Salmon, L ;

Tuchagues, JP ;

Bousseksou, A ;

Real, JA .

INORGANIC CHEMISTRY, 2002, 41 (26) :6997-7005

[10] ELECTRON-PARAMAGNETIC-RES STUDY OF MANGANESE(II) IN 2 CRYSTALLINE FORMS OF FE(C6H8N2S2)2(NCS)2 AND THE HIGH-SPIN LOW-SPIN TRANSITION THAT OCCURS IN ONLY ONE FORM - X-RAY STRUCTURE DETERMINATION OF BOTH FORMS [J].

OZAROWSKI, A ;

MCGARVEY, BR ;

SARKAR, AB ;

DRAKE, JE .

INORGANIC CHEMISTRY, 1988, 27 (04) :628-635