How reaction kinetics with time-dependent rate coefficients differs from generalized mass action

被引：19
作者：
Grima, Ramon
Schnell, Santiago
机构：
[1] Indiana Univ, Sch Informat, Bloomington, IN 47406 USA
[2] Indiana Univ, Biocomplex Inst, Bloomington, IN 47406 USA
来源：
CHEMPHYSCHEM | 2006年 / 7卷 / 07期
关键词：
kinetics; reaction mechanisms; low-dimensional media; intracellular environments; time-dependent rate coefficients;
D O I：
10.1002/cphc.200600081
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
(Graph Presented) Take caution! The two distinct theoretical descriptions of non-classical kinetics: fractal-like kinetics (kinetics with time-dependent rate coefficients) and the power law approximation (generalized mass action kinetics) are shown to be equivalent only for simple reactions of the type A+A→ø or A+B→ø with equal initial concentrations of A and B. In all other cases they are not the same. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：1422 / 1424
页数：3
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