Cyclometalated Complexes of Platinum( II) with 2-Vinylpyridine

被引：18

作者：

Zucca, Antonio ^{[1
]}

Maidich, Luca ^{[1
]}

Carta, Veronica ^{[1
]}

Petretto, Giacomo L. ^{[1
]}

Stoccoro, Sergio ^{[1
]}

Cinellu, Maria Agostina ^{[1
]}

Pilo, Maria I. ^{[1
]}

Clarkson, Guy J. ^{[2
]}

机构：

[1] Univ Sassari, Dipartimento Chim & Farm, I-07100 Sassari, Italy

[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2014年 / 2014卷 / 13期

关键词：

Metallacycles; Metalation; C-H activation; Platinum; Vinylidene ligands; C-H ACTIVATION; ELECTRONIC-STRUCTURE; MOLECULAR-STRUCTURE; TRANSITION-METALS; CRYSTAL-STRUCTURE; DERIVATIVES; LIGAND; OSMIUM; METALATION; INSERTION;

D O I：

10.1002/ejic.201400052

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The electron-rich platinum(II) derivatives [Pt(R)(2)(DMSO)(2)] (R = Me, Ph) react with 2-vinylpyridine (L) to give the cyclometalated complexes [Pt(L-H)(R)(DMSO)] through C-H bond activation. Cyclometalation also occurs with [Pt(Me)(Cl)(DMSO)(2)]. From the starting compounds, a series of cyclometalated complexes was obtained and characterised by analytical and spectroscopic methods. The molecular structures of [Pt(L-H)(Me)(PPh3)] and [Pt(L-H)(Ph)(PCy3)] were solved by X-ray diffraction analysis, and the results unambiguously demonstrate cyclometalation of 2-vinylpyridine. The five-membered cyclometalated ring is particularly stable, likely due to partial electronic delocalisation.

引用

收藏

页码：2278 / 2287

页数：10

相关论文

共 83 条

[21] Displacement of phenyl and styryl ligands by benzophenone imine and 2-vinylpyridine on ruthenium and osmium [J].

Buil, Maria L. ;

Esteruelas, Miguel A. ;

Goni, Eva ;

Olivan, Montserrat ;

Onate, Enrique .

ORGANOMETALLICS, 2006, 25 (12) :3076-3083

[22] METALATION OF 2-ETHENYLPYRIDINE AT TRIOSMIUM CLUSTERS - X-RAY CRYSTAL-STRUCTURES OF THE OPEN TRINUCLEAR CLUSTERS [OS3H(CO)9CO(NC5H4CH=CH)], [OS3H(CO)9PME2PH(NC5H4CH=CH)] [J].

BURGESS, K ;

HOLDEN, HD ;

JOHNSON, BFG ;

LEWIS, J ;

HURSTHOUSE, MB ;

WALKER, NPC ;

DEEMING, AJ ;

MANNING, PJ ;

PETERS, R .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (01) :85-90

[23] CIS-BIS(2-PHENYLPYRIDINE)PLATINUM(II) (CBPPP) - A SIMPLE MOLECULAR PLATINUM COMPOUND [J].

CHASSOT, L ;

MULLER, E ;

VONZELEWSKY, A .

INORGANIC CHEMISTRY, 1984, 23 (25) :4249-4253

[24]

Chen Y., 2009, ANGEW CHEM, V121, P10093

[25] Photoresponsive Supramolecular Organometallic Nanosheets Induced by PtII•••PtII and C-H•••π Interactions [J].

Chen, Yong ;

Li, Kai ;

Lu, Wei ;

Chui, Stephen Sin-Yin ;

Ma, Chun-Wah ;

Che, Chi-Ming .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (52) :9909-9913

[26] Gold(III) adducts of 2-vinyl- and 2-ethylpyridine and cyclometallated derivatives of 2-vinylpyridine: Crystal structure of the cyclometallated derivative [Au(k2-C,N-CH2CH(Cl)-C5H4N)(PPh3)Cl][PF6] [J].

Cinellu, Maria Agostina ;

Cocco, Fabio ;

Minghetti, Giovanni ;

Stoccoro, Sergio ;

Zucca, Antonio ;

Manassero, Mario .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (18) :2949-2955

[27] Reactivity of [RuHCl(PiPr3)2]2 with functionalized vinyl substrates.: The H2 ligand as a sensitive probe of electronic structure [J].

Coalter, JN ;

Streib, WE ;

Caulton, KG .

INORGANIC CHEMISTRY, 2000, 39 (17) :3749-3756

[28]

Crabtree RH, 2005, ORGANOMETALLIC CHEMISTRY OF THE TRANSITION METALS, 4TH EDITION, P1, DOI 10.1002/0471718769

[29] Heteropolynuclear cycloplatinated complexes: Structural and photophysical properties [J].

Diez, Alvaro ;

Lalinde, Elena ;

Teresa Moreno, M. .

COORDINATION CHEMISTRY REVIEWS, 2011, 255 (21-22) :2426-2447

[30] OLEX2: a complete structure solution, refinement and analysis program [J].

Dolomanov, Oleg V. ;

Bourhis, Luc J. ;

Gildea, Richard J. ;

Howard, Judith A. K. ;

Puschmann, Horst .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2009, 42 :339-341

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