Di-μ-chlorido-bis{aquachlorido[2,2′-thiobis(pyridine N-oxide)-κO]copper(II)}

被引:2
作者
Seidel, Ruediger W. [1 ]
Oppel, Iris M. [1 ]
机构
[1] Ruhr Univ Bochum, D-44780 Bochum, Germany
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
D O I
10.1107/S1600536809011076
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The crystal structure of the title compound, [Cu(2)Cl(4)(C(10)H(8)N(2)O(2)S)(2)(H(2)O)(2)], comprises neutral centrosymmetric mu-chloride-bridged dinuclear units. Each Cu(II) ion is pentacoordinated by three chloride ligands, a pyridine N-oxide O atom and a water molecule. Intra- and intermolecular O-H center dot center dot center dot O hydrogen bonds occur between the coordinated water molecules and the uncoordinated and coordinated pyridine N-oxide groups of the 2,2'-thiobis(pyridine N-oxide) ligands, respectively.
引用
收藏
页码:M460 / U1056
页数:9
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