Three new insecticidal sesquiterpene pyridine alkaloids from Celastrus angulatus

被引:17
作者
Ji Zhiqing [1 ]
Zhang Qidong [1 ]
Shi Baojun [1 ]
Wei Shaopeng [1 ]
Wang Mingan [2 ]
Wu Wenjun [2 ]
机构
[1] NW Agr Univ, Dept Plant Protect, Yangling, Shaanxi, Peoples R China
[2] China Agr Univ, Dept Appl Chem, Beijing 100094, Peoples R China
关键词
Celastraceae; Celastrus angulatus; insecticide; -dihydroagarofuran sesquiterpene; celangulatin; POLYOL ESTERS; TRIPTERYGIUM-HYPOGLAUCUM; CHINESE BITTERSWEET; ORBICULATUS; CELANGULIN; AGENTS;
D O I
10.1080/14786410802086217
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Three new sesquiterpene pyridine alkaloids with a -dihydroagarofuran sesquiterpene skeleton, celangulatin G(1), H(2) and I(3), and one known alkaloid 4 were isolated from the middle-polar extracts of the root bark of Celastrus angulatus by bioassay-guided separation. Their chemical structures were elucidated mainly by the analyses of the MS and NMR spectral data. Celangulatin G(1), H(2), I(3) and 4 showed KD50 against Mythimna separata were 849.61, 80.24, 96.29 and 50.98 g g-1, respectively.
引用
收藏
页码:470 / 478
页数:9
相关论文
共 27 条
  • [1] BRUNING R, 1978, PHYTOCHEMISTRY, V17, P1821, DOI 10.1016/S0031-9422(00)88719-1
  • [2] Antitumor agents.: 228.: Five new agarofurans, reissantins A-E, and cytotoxic principles from Reissantia buchananiii
    Chang, FR
    Hayashi, K
    Chen, IH
    Liaw, CC
    Bastow, KF
    Nakanishi, Y
    Nozaki, H
    Cragg, GA
    Wu, YC
    Lee, KH
    [J]. JOURNAL OF NATURAL PRODUCTS, 2003, 66 (11): : 1416 - 1420
  • [3] Chen F, 1999, CLIN CHEM, V45, P7
  • [4] Immunosuppressive sesquiterpene alkaloids from Tripterygium wilfordii
    Duan, HQ
    Takaishi, Y
    Momota, H
    Ohmoto, Y
    Taki, T
    Jia, YF
    Li, D
    [J]. JOURNAL OF NATURAL PRODUCTS, 2001, 64 (05): : 582 - 587
  • [5] Sesquiterpene polyol esters from Tripterygium wilfordii
    Duan, HQ
    Takaishi, Y
    Jia, YF
    Li, D
    [J]. PHYTOCHEMISTRY, 2001, 56 (04) : 341 - 346
  • [6] Novel sesquiterpene esters with alkaloid and monoterpene and related compounds from Tripterygium hypoglaucum:: A new class of potent anti-HIV agents
    Duan, HQ
    Takaishi, Y
    Bando, M
    Kido, M
    Imakura, Y
    Lee, KH
    [J]. TETRAHEDRON LETTERS, 1999, 40 (15) : 2969 - 2972
  • [7] Sesquiterpene alkaloids from Tripterygium hypoglaucum and Tripterygium wilfordii:: A new class of potent anti-HIV agents
    Duan, HQ
    Takaishi, Y
    Imakura, Y
    Jia, YF
    Li, D
    Cosentino, LM
    Lee, KH
    [J]. JOURNAL OF NATURAL PRODUCTS, 2000, 63 (03): : 357 - 361
  • [8] Sesquiterpene alkaloids from Tripterygium hypoglaucum
    Duan, HQ
    Kawazoe, K
    Takaishi, Y
    [J]. PHYTOCHEMISTRY, 1997, 45 (03) : 617 - 621
  • [9] Sesquiterpene evoninate alkaloids from Tripterygium hypoglaucum
    Duan, HQ
    Takaishi, Y
    [J]. PHYTOCHEMISTRY, 1999, 52 (08) : 1735 - 1738
  • [10] Four novel insecticidal sesquiterpene esters from Celastrus angulatus
    Ji, Zhiqing
    Wu, Wenjun
    Yang, Hua
    Shi, Baojun
    Wang, Mingan
    [J]. NATURAL PRODUCT RESEARCH, 2007, 21 (04) : 334 - 342