Recent advances in B-H functionalization of icosahedral carboranes and boranes by transition metal catalysis

被引：69

作者：

Duttwyler, Simon ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China

来源：

PURE AND APPLIED CHEMISTRY | 2018年 / 90卷 / 04期

基金：

中国国家自然科学基金;

关键词：

B-H activation; boranes; carboranes; catalysis; cluster; IMEBORON-16; transition metals; BORON-HYDROGEN BONDS; O-CARBORANES; PROMOTED REACTIONS; MEDIATED FUNCTIONALIZATION; OXIDATIVE ADDITION; IRIDIUM; ACTIVATION; HYDRIDES; HYDROBORATIONS; PHARMACOPHORES;

D O I：

10.1515/pac-2017-1202

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Significant progress in the functionalization of icosahedral boron clusters has been made in the past years, leading to an increasing number of applications in various fields of research. The direct conversion of B-H bonds to substituted vertices constitutes an attractive strategy to synthesize cage compounds with desired properties. In this report, recent advances in the transition metal-catalyzed B-H activation of neutral and anionic boron clusters are presented.

引用

页码：733 / 744

页数：12

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